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Dicyclohexylphosphine

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Dicyclohexylphosphine Basic information

Product Name:
Dicyclohexylphosphine
Synonyms:
  • DICYCLOHEXYLPHOSPHINE
  • dicyclohexyl-phosphin
  • Dicyclohexylphosphine,98%
  • Dicyclohexylphosphine,98%(10wt%inhexane)
  • Bis(cyclohexyl)phosphine
  • dicyclohexylphosphane
  • DICYCLOHEXYLPHOSPHINE (10% WT. IN HEXANE)
  • 98% Cy2PH
CAS:
829-84-5
MF:
C12H23P
MW:
198.28
EINECS:
212-590-9
Product Categories:
  • Secondary Phosphines
  • organophosphorus ligand
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Phosphorus Precursors
Mol File:
829-84-5.mol
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Dicyclohexylphosphine Chemical Properties

Melting point:
2°C
Boiling point:
129 °C 8 mm Hg
Density 
0,98 g/cm3
refractive index 
n 20/D 1.516
Flash point:
2 °C
form 
liquid
color 
colorless to light yellow
Specific Gravity
0.98
Hydrolytic Sensitivity
9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
Sensitive 
air sensitive
InChI
InChI=1S/C12H23P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2
InChIKey
HDULBKVLSJEMGN-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)C1CCCCC1
CAS DataBase Reference
829-84-5
EPA Substance Registry System
Phosphine, dicyclohexyl- (829-84-5)
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Safety Information

Hazard Codes 
F,T
Risk Statements 
17-23/24/25
Safety Statements 
17-36/37/39-45
RIDADR 
UN 2845 4.2/PG 1
TSCA 
No

MSDS

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Dicyclohexylphosphine Usage And Synthesis

Uses

Wang et al. developed a novel fluorescent probe based on dicyclohexylphosphine for rapid and sensitive detection of HOCl in an aqueous solution. The probe exhibits a significant fluorescence turn-on response to HOCl through the specific oxidative reaction between dicyclohexylphosphine and HOCl[1].

References

[1] Bi, Sheng et al. “A phosphine-based fluorescent probe for fluorescent imaging of hypochlorous acid in living cells and zebrafish?.” New Journal of Chemistry 25 (2023): 11912–11918.
[2] F.G. Moers, J.J. Steggerda, D.H.M.W. Thewissen. “Dicyclohexylphosphinodithioformate complexes and dicylohexylphosphine complexes.” Journal of Inorganic and Nuclear Chemistry 39 8 (1977): Pages 1321-1322.

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