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1,2,4-TRIBROMOBENZENE

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1,2,4-TRIBROMOBENZENE Basic information

Product Name:
1,2,4-TRIBROMOBENZENE
Synonyms:
  • 1,2,4-Tribomobenzene
  • 1,2,4-tribromo-benzen
  • 1,2,4-TRIBROMOBENZENE
  • 1,2,4-Tribromobenzene,95%
  • NSC 62440
  • 1,2,4-Tribromobenzene>
  • Benzene, 1,2,4-tribromo-
  • 1,2,4-TRIBROMOBENZENE ISO 9001:2015 REACH
CAS:
615-54-3
MF:
C6H3Br3
MW:
314.8
EINECS:
210-433-9
Product Categories:
  • Bromine Compounds
  • Aryl
  • C6
  • Halogenated Hydrocarbons
  • Building Blocks
  • Chemical Synthesis
  • Halogenated Hydrocarbons
  • Organic Building Blocks
Mol File:
615-54-3.mol
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1,2,4-TRIBROMOBENZENE Chemical Properties

Melting point:
41-43 °C (lit.)
Boiling point:
275 °C
Density 
2.3515 (estimate)
refractive index 
>110^o(230^oF)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form 
powder to crystal
color 
White to Light yellow to Light orange
Water Solubility 
Insoluble in water.
BRN 
1934823
InChIKey
FWAJPSIPOULHHH-UHFFFAOYSA-N
CAS DataBase Reference
615-54-3(CAS DataBase Reference)
EPA Substance Registry System
1,2,4-Tribromobenzene (615-54-3)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
RTECS 
DC1956500
TSCA 
Yes
HS Code 
2903.99.8001

MSDS

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1,2,4-TRIBROMOBENZENE Usage And Synthesis

Chemical Properties

WHITE CRYSTALLINE POWDER

Uses

1,2,4-tribromobenzene is used in the synthesis of hyper branched poly(p-phenylene ethynylenes). It is used as cross-linking reagent during Pd-catalyzed cross-coupling of 2,5-diiodo-4-[(2-ethylhexyl)oxy]methoxybenzene and 1,4-diethynyl-2,5-bis-(octyloxy)benzene. It is a compound commonly used in organic synthesis reactions.

General Description

1,2,4-tribromobenzene on photochemical dehalogenation in open-air solutions of acetonitrile yields 1,4-dibromobenzene, 1,3-dibromobenzene and 1,2-dibromobenzene.

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