Basic information Reaction Safety Supplier Related

[Ir{dFCF3ppy}2(bpy)]PF6

Basic information Reaction Safety Supplier Related

[Ir{dFCF3ppy}2(bpy)]PF6 Basic information

Product Name:
[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms:
  • [Ir{dFCF3ppy}2(bpy)]PF6
  • Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate
  • (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE
  • Ir[dF(CF3)2ppy]2(bpy)]PF6
  • (2,2'-Bipyridine)bis[3,5-difL
  • uoro-2-[5-trifL
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
CAS:
1092775-62-6
MF:
C34H18F16IrN4P
MW:
1009.6987322
Mol File:
1092775-62-6.mol
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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
yellow
Sensitive 
air sensitive
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[Ir{dFCF3ppy}2(bpy)]PF6 Usage And Synthesis

Reaction

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

[Ir{dFCF3ppy}2(bpy)]PF6Supplier

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