[Ir{dFCF3ppy}2(bpy)]PF6
[Ir{dFCF3ppy}2(bpy)]PF6 Basic information
- Product Name:
- [Ir{dFCF3ppy}2(bpy)]PF6
- Synonyms:
-
- [Ir{dFCF3ppy}2(bpy)]PF6
- Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate
- (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE
- Ir[dF(CF3)2ppy]2(bpy)]PF6
- (2,2'-Bipyridine)bis[3,5-difL
- uoro-2-[5-trifL
- (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate
- (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
- CAS:
- 1092775-62-6
- MF:
- C34H18F16IrN4P
- MW:
- 1009.6987322
- Mol File:
- 1092775-62-6.mol
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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
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[Ir{dFCF3ppy}2(bpy)]PF6 Usage And Synthesis
Reaction
- Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
- Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
- Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
- Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
- Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
- Photocatalyst used in the cross-coupling of trifluoroalkylboranes.
Uses
When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.
[Ir{dFCF3ppy}2(bpy)]PF6Supplier
Tianjin Kailiqi Biotechnology Co., Ltd. Gold
- Tel
- 15076683720
- klq@cw-bio.com
Beijing HwrkChemical Technology Co., Ltd
- Tel
- 010-89508211 18501085097
- sales.bj@hwrkchemical.com
Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
TOKYO CHEMICAL INDUSTRY CO., LTD.
- Tel
- 03-36680489
- Sales-JP@TCIchemicals.com
TCI Europe
- Tel
- 320-37350700
- sales@tcieurope.eu
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[Ir{dFCF3ppy}2(bpy)]PF6(1092775-62-6)Related Product Information
- Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III)
- Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
- Ir[dF(t-Bu)-ppy]3
- (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
- Iridium
- [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
- (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
- Tris (2- (4-tert-butylphenyl) pyridine) iridium
- Ir[dF(Me)ppy]2(dtbbpy)PF6
- Ir(dFppy)3
- (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
- Ir[p-F(t-Bu)-ppy]3
- [Ir(dtbbpy)(ppy)2][PF6]
- Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
- Ir[dFppy]2(dtbbpy)PF6
- hexafluorophosphate
- Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
- Ir[p-F(Me)ppy]2(dtbbpy)PF6