Ir[p-F(t-Bu)-ppy]3 Chemical Properties

Melting point:

372.5°C

form 

powder or crystals

InChI

1S/3C15H15FN.Ir/c3*1-15(2,3)12-8-9-17-14(10-12)11-4-6-13(16)7-5-11;/h3*4,6-10H,1-3H3;

InChIKey

KBFAZTBWJUCETR-UHFFFAOYSA-N

SMILES

[Ir](c5c(ccc(c5)F)c6nccc(c6)C(C)(C)C)(c3c(ccc(c3)F)c4nccc(c4)C(C)(C)C)c1c(ccc(c1)F)c2nccc(c2)C(C)(C)C

Safety Information

WGK Germany 

WGK 3

Storage Class

11 - Combustible Solids

Ir[p-F(t-Bu)-ppy]3 Usage And Synthesis

Uses

Ir[p-F(t-Bu)-ppy]₃ is a photocatalyst which readily facilitates the decarboxylative arylation of α amino acids using visible light.

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

Ir[p-F(t-Bu)-ppy]3(1311386-93-2)Related Product Information

• tris-(1,10-phenanthroline)ruthenium
• Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III)
• Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
• Ir[dF(t-Bu)-ppy]3
• (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
• Iridium
• [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
• (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
• Tris (2- (4-tert-butylphenyl) pyridine) iridium
• Ir[dF(Me)ppy]2(dtbbpy)PF6
• Ir(dFppy)3
• (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
• [Ir{dFCF3ppy}2(bpy)]PF6
• [Ir(dtbbpy)(ppy)2][PF6]
• Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
• Ir[dFppy]2(dtbbpy)PF6
• hexafluorophosphate
• Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)