2-Methyl-3-biphenylmethanol
2-Methyl-3-biphenylmethanol Basic information
- Product Name:
- 2-Methyl-3-biphenylmethanol
- Synonyms:
-
- 2-Methyl-3-biphenylm
- 2-Methyl-3-phenylbenzyl Alcohol
- [1,1'-Biphenyl]-3-Methanol,2-Methyl-
- Bifenthrin alcohol metabolite, 10 μg /μL in cyclohexane
- (2-Methyl[1,1'-biphenyl]- 3-yl) methanol (bifenthrin alcohol, BFA, BA)
- 2-METHYLBIPHENYL-3-METHANOL
- 2-METHYL-3-BIPHENYLMETHANOL
- 3-HYDROXYMETHYL-2-METHYLBIPHENYL
- CAS:
- 76350-90-8
- MF:
- C14H14O
- MW:
- 198.26
- EINECS:
- 1312995-182-4
- Product Categories:
-
- Pesticide
- Alkohols
- Alcohols
- C9 to C30
- Oxygen Compounds
- Aromatics
- Aromatic alcohols and diols
- Intermediates & Fine Chemicals
- Pharmaceuticals
- Mol File:
- 76350-90-8.mol
2-Methyl-3-biphenylmethanol Chemical Properties
- Melting point:
- 73-76 °C(lit.)
- Boiling point:
- 330.9±11.0 °C(Predicted)
- Density
- 1.072±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Solid
- pka
- 14.28±0.10(Predicted)
- color
- White to Off-White
- InChI
- InChI=1S/C14H14O/c1-11-13(10-15)8-5-9-14(11)12-6-3-2-4-7-12/h2-9,15H,10H2,1H3
- InChIKey
- BGTLHJPGBIVQLJ-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)=CC=CC(CO)=C1C
- CAS DataBase Reference
- 76350-90-8(CAS DataBase Reference)
- EPA Substance Registry System
- [1,1'-Biphenyl]-3-methanol, 2-methyl- (76350-90-8)
MSDS
- Language:English Provider:SigmaAldrich
2-Methyl-3-biphenylmethanol Usage And Synthesis
Description
2-Methyl-3-biphenylmethanol is a pharmaceutical intermediate and organic chemical synthesis reagent, which can be used in the preparation of drugs such as Bifenthrin and PD-L1 inhibitors, and also in the synthesis of other organic compounds such as 2-methyl-3-phenylphenethylboronic acid pinacol ester, biphenyl-1,2,3-triazole couplings and biphenyl alcohols.
Chemical Properties
white to light yellow crystal powde
Uses
Bifenthrin intermediate.
Synthesis
Carrying out a Suzuki coupling reaction between 3-bromo-2-methylbenzoic acid and phenyl substituted boric acid or phenyl substituted borate to obtain 3-phenyl-2-methylbenzoic acid, and then carrying out a reduction reaction to obtain 2-Methyl-3-biphenylmethanol, wherein the Suzuki coupling reaction is carried out at 10-150 DEG C for 1-12 hours under the action of an alkali. 3-phenyl-2-methylbenzoic acid can be directly reduced with a reducing agent such as borane and lithium aluminium hydride to obtain 2-Methyl-3-biphenylmethanol.
2-Methyl-3-biphenylmethanol Preparation Products And Raw materials
Raw materials
Preparation Products
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