Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties

Melting point:

159 °C

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene

form 

Solution

color 

Clear

Water Solubility 

insoluble

Sensitive 

Air & Moisture Sensitive

Hydrolytic Sensitivity

8: reacts rapidly with moisture, water, protic solvents

BRN 

4935939

InChI

InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2

InChIKey

QUVLSIIMVTXAPD-UHFFFAOYSA-M

SMILES

P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl

CAS DataBase Reference

15529-49-4(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22-20/21

Safety Statements 

36/37-22

RIDADR 

2811

WGK Germany 

3

TSCA 

No

HS Code 

28439000

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis

Chemical Properties

black crystals

Uses

suzuki reaction

Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Preparation

Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol  according to the procedure of Wilkinson.

General Description

Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols.

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

Tris(triphenylphosphine)ruthenium(II) chloride(15529-49-4)Related Product Information

• Tricine
• Tris(hydroxymethyl)aminomethane
• Ruthenium(III) chloride
• Ruthenium
• Tris(triphenylphosphine)rhodiu
• BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
• TRIPHENYLPHOSPHINE DIBROMIDE
• BIS-Tris
• Triphenylphosphine
• Potassium chloride
• cis-Bis(triphenylphosphine)platinum(II) chloride
• Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
• Triphenylphosphine oxide
• Bis(triphenylphosphine)palladium(II) chloride
• CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
• Tetrakis(triphenylphosphine)platinum
• Allylpalladium(II) Chloride Dimer
• Bis(tri-tert-butylphosphine)palladium(0)