Tris(triphenylphosphine)ruthenium(II) chloride CAS#: 15529-49-4

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Tris(triphenylphosphine)ruthenium(II) chloride

Basic information Safety Supplier Related

Tris(triphenylphosphine)ruthenium(II) chloride Basic information

Product Name:

Tris(triphenylphosphine)ruthenium(II) chloride

Synonyms:

RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE)
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
Tris(triphenylphosphine)ruthenium(II) chloride≥ 99.5% (Assay)
Tris(triphenylphosphine)ruthenium(II) chloride (10.5% Ru) for synthesis
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)

CAS:

15529-49-4

MF:

C54H45Cl2P3Ru

MW:

958.83

EINECS:

239-569-7

Product Categories:

Ru
metal-phosphine complexes
Catalysts for Organic Synthesis
Classes of Metal Compounds
Environmentally-friendly Oxidation
Homogeneous Catalysts
Metal Compounds
Metal Complexes
Ru (Ruthenium) Compounds
Synthetic Organic Chemistry
Transition Metal Complexes (Environmentally-friendly Oxidation)
Transition Metal Compounds
chemical reaction,pharm,electronic,materials

Mol File:

15529-49-4.mol

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Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties

Melting point:: 159 °C
storage temp.: Inert atmosphere,Room Temperature
solubility: Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form: Solution
color: Clear
Water Solubility: insoluble
Sensitive: Air & Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 4935939
InChI: InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKey: QUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILES: P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
CAS DataBase Reference: 15529-49-4(CAS DataBase Reference)

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Safety Information

Hazard Codes: Xn
Risk Statements: 20/21/22-20/21
Safety Statements: 36/37-22
RIDADR: 2811
WGK Germany: 3
TSCA: No
HS Code: 28439000

MSDS

Language:English Provider:ACROS
Language:English Provider:SigmaAldrich
Language:English Provider:ALFA

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Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis

Chemical Properties

black crystals

Uses

suzuki reaction

Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials

Raw materials

Etanol Tetrahydrofuran Dichloromethane Isopropanol Hydrazinium hydroxide Triphenylphosphine Litium Ruthenium(III) chloride

Tris(triphenylphosphine)ruthenium(II) chlorideSupplier

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