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Tris(triphenylphosphine)ruthenium(II) chloride

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Tris(triphenylphosphine)ruthenium(II) chloride Basic information

Product Name:
Tris(triphenylphosphine)ruthenium(II) chloride
Synonyms:
  • RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
  • RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE)
  • TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE
  • TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE
  • TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
  • Tris(triphenylphosphine)ruthenium(II) chloride≥ 99.5% (Assay)
  • Tris(triphenylphosphine)ruthenium(II) chloride (10.5% Ru) for synthesis
  • DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
CAS:
15529-49-4
MF:
C54H45Cl2P3Ru
MW:
958.83
EINECS:
239-569-7
Product Categories:
  • Ru
  • metal-phosphine complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Environmentally-friendly Oxidation
  • Homogeneous Catalysts
  • Metal Compounds
  • Metal Complexes
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Complexes (Environmentally-friendly Oxidation)
  • Transition Metal Compounds
  • chemical reaction,pharm,electronic,materials
Mol File:
15529-49-4.mol
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Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties

Melting point:
159 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form 
Solution
color 
Clear
Water Solubility 
insoluble
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
4935939
InChI
InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKey
QUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
CAS DataBase Reference
15529-49-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-20/21
Safety Statements 
36/37-22
RIDADR 
2811
WGK Germany 
3
TSCA 
No
HS Code 
28439000

MSDS

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Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis

Chemical Properties

black crystals

Uses

suzuki reaction

Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials

Raw materials

EtanolTetrahydrofuranDichloromethaneIsopropanolHydrazinium hydroxideTriphenylphosphineLitiumRuthenium(III) chloride

Tris(triphenylphosphine)ruthenium(II) chlorideSupplier

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