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Benzyltrimethylammonium bromide

Basic information Safety Supplier Related

Benzyltrimethylammonium bromide Basic information

Product Name:
Benzyltrimethylammonium bromide
Synonyms:
  • [BzM3N]Br
  • Benzyltrimethylammonium bromide≥ 99% (Assay)
  • TRIMETHYLBENZYLAMMONIUM BROMIDE
  • TRIMETHYLAMMONIUM BROMIDE
  • (Benzyltrimethyl)ammonium bromide(btm)
  • Ammonium, (benzyltrimethyl)-, bromide
  • Benzenemethanaminium, N,N,N-trimethyl-, bromide
  • Benzyltrimenthylammoniumbromi
CAS:
5350-41-4
MF:
C10H16BrN
MW:
230.14
EINECS:
226-320-2
Product Categories:
  • Ammonium Salts
  • Greener Alternatives: Catalysis
  • Pharmaceutical Intermediates
  • Quaternary Ammonium Compounds
  • Phase Transfer Catalysts
  • Quaternary ammonium salt
  • Ammonium Bromides (Quaternary)
Mol File:
5350-41-4.mol
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Benzyltrimethylammonium bromide Chemical Properties

Melting point:
230-232 °C (lit.)
storage temp. 
Inert atmosphere,Room Temperature
Water Solubility 
Soluble in water
form 
Crystalline Powder
color 
White to off-white
Sensitive 
Hygroscopic
BRN 
3917251
CAS DataBase Reference
5350-41-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzyltrimethylammonium bromide(5350-41-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN 2811
WGK Germany 
3
RTECS 
BO8392000
3
Hazard Note 
Irritant
HS Code 
29239000
Toxicity
LD50 subcutaneous in mouse: 45mg/kg

MSDS

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Benzyltrimethylammonium bromide Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Benzyltrimethylammonium bromide (BTMAB) can be used as a starting material for the synthesis of benzyltrimethylammonium fluorochromate (BTMAFC) by treating with an aqueous solution of CrO3 and HF. BTMAFC can be utilized as an efficient oxidizing reagent for the selective oxidation of oximes into ketones or aldehydes, and primary, secondary, allylic as well as benzylic alcohols to their corresponding carbonyl compounds.

BTMAB can be also used as:??????

  • An oxidizing reagent for the conversion of monosubstituted benzylamines into corresponding aldimines in the presence of DMSO.??????
  • A benzylating reagent for the benzylation of aryl amide C-H bond using Ni catalyst.

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