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BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE

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BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information

Product Name:
BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:
  • Bis(norbornadiene)rhodium(I)tetrafluoroborate Also avilable as trifluoromethanesulfonate and hexafluorophosphate
  • Bis(norbornadiene)rhodium(I) Tetrafluoroborate (Rh(nbd)2BF4)
  • BIS(NORBORNADIENE)RHODIUM(I) TETRAFLUOR&
  • Bis(norbornadiene)rhodium(I)tetrafluoroborate,min.96%
  • BIS[ETA/-(2,5-NORBORNADIENE)]RHODIUM(I) TERTAFLUOROBORATE
  • [Rh(ndb)2]BF4
  • Bis(norbornadiene)rhodium(I) tetrafluoroborate, 27% Rh, Product of Umicore
  • Bis(norbornadiene)rhodium(I) tet
CAS:
36620-11-8
MF:
C14H8BF4Rh
MW:
365.93
Product Categories:
  • Triazoles ,Triazines
  • Rh
  • Tetrafluoroborates
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • organometallic complex
  • B (Classes of Boron Compounds)
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Chemical Synthesis
  • Rhodium
  • Synthetic Organic Chemistry
Mol File:
36620-11-8.mol
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BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties

Melting point:
209-211 °C
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
Powder
color 
Red
Water Solubility 
Fairly soluble in dichloromethane. Insoluble in water.
Sensitive 
Air & Moisture Sensitive
InChIKey
NMZDXSXETNAOPO-UHFFFAOYSA-M
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Safety Information

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
16-45-36/37/39-26
RIDADR 
1325
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
28439000

MSDS

  • Language:English Provider:ACROS
  • Language:English Provider:ALFA
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BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis

Chemical Properties

dark red

Uses

Bis(norbornadiene)rhodium(I) tetrafluoroborate is used in hydrogenation, Isomerization reactions.

Uses

Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.

Reactions

Precursor for asymmetric hydrogenation reactions.

BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATESupplier

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