Tris(tetrabutylammonium) hydrogen pyrophosphate Chemical Properties

Melting point:

145 - 148°C

storage temp. 

2-8°C

solubility 

Methanol (Slightly), Water (Slightly)

form 

Solid

color 

White to Light Yellow

BRN 

4632762

Stability:

Hygroscopic

InChI

InChI=1S/C16H36N.H4O7P2/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-8(2,3)7-9(4,5)6/h5-16H2,1-4H3;(H2,1,2,3)(H2,4,5,6)/q+1;/p-3

InChIKey

BMTUFQKYWWLCLC-UHFFFAOYSA-K

SMILES

[N+](CCCC)(CCCC)(CCCC)CCCC.O(P(O)([O-])=O)P([O-])([O-])=O

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

WGK Germany 

3

F 

3-10

MSDS

• Language:English Provider:SigmaAldrich

Tris(tetrabutylammonium) hydrogen pyrophosphate Usage And Synthesis

Description

Tris(tetrabutylammonium) hydrogen pyrophosphate is a reagent used for pyrophosphorylation, reactions involving isoprenoid derivatives, and the pyrophosphorylation and triphosphorylation of nucleosides.
Tris(tetrabutylammonium) hydrogen pyrophosphate. A new reagent for the preparation of allylic pyrophosphate esters

Chemical Properties

White Crystalline Powder

Uses

Phosphorylating reagent.

Application

Tris(tetrabutylammonium) hydrogen pyrophosphate was used for:
Reagent for pyrophosphorylation
reaction of isoprenoid derivatives
Pyrophosphorylation of nucleosides
Triphosphorylation of nucleosides

General Description

Tris(tetrabutylammonium) hydrogen pyrophosphate is a triphosphate that is used as a nucleophile in organic synthesis. It reacts with isopropyl alcohol to form the corresponding cyclic adducts, which can be isolated as the corresponding acetonitrile salts. Tris(tetrabutylammonium) hydrogen pyrophosphate is also used as an intermediate for the synthesis of other molecules, such as geranyl, and provides a predictable means of synthesizing isotopomers of these molecules. This molecule may be prepared by reacting ammonium bicarbonate with chloride and then adding isopropyl alcohol to the mixture.

Tris(tetrabutylammonium) hydrogen pyrophosphate(76947-02-9)Related Product Information

• Tetrabutylammonium fluoride
• Pyrophosphoric acid
• Tetrabutylammonium phosphate
• Tris(tetrabutylammonium) hydrogen pyrophosphate
• Tributylammonium pyrophosphate
• TETRABUTYLAMMONIUM HYPOPHOSPHITE