ChemicalBook > Product Catalog > Organic Chemistry > Nitrile compound > Tris(acetonitrile)tricarbonyltungsten
Tris(acetonitrile)tricarbonyltungsten
Tris(acetonitrile)tricarbonyltungsten Basic information
- Product Name:
- Tris(acetonitrile)tricarbonyltungsten
- Synonyms:
-
- tris(acetonitrile)tricarbonyl-tungste
- TRIS(ACETONITRILE)TRICARBONYLTUNGESTEN(&
- tris(acetonitrile)tricarbonyltungsten(0)
- tris(acetonitrile)tungsten(0)
- Tris(acetonitryl)tungsten tricarbonyl
- Tricarbonyl tris(acetonitrile)tungsten
- Tris(acetonitrile)tungsten tricarbonyl
- TRIS(ACETONITRILE)TRICARBONYLTUNGSTEN
- CAS:
- 16800-47-8
- MF:
- C9H9N3O3W
- MW:
- 391.03
- EINECS:
- 240-833-9
- Mol File:
- 16800-47-8.mol
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Tris(acetonitrile)tricarbonyltungsten Chemical Properties
- Melting point:
- >300 °C(lit.)
- Boiling point:
- 34°C
- solubility
- sol acetonitrile, nitromethane
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Safety Information
- Hazard Codes
- T+
- Risk Statements
- 26/27/28
- Safety Statements
- 28-36/37-45-7/9
- RIDADR
- UN 3466 6.1/PG 1
- WGK Germany
- 3
- RTECS
- YO7800000
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Tris(acetonitrile)tricarbonyltungsten Usage And Synthesis
Uses
Catalyst for allylic substitutions
Reactant for:
- Mixed disilyl-substituted cyclopentadiene derivatives
- Synthesis of catalytically active ansa compounds with cycloalkyl moieties
- Stepwise assembly of mixed metal dinuclear carbonyl complexes
- Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes
Preparation
By refluxing Hexacarbonyltungsten in Acetonitrile in an inert atmosphere. Removal of solvent under an inert atmosphere yields tris(acetonitrile)tricarbonyltungsten. Solutions of the reagent can be prepared by photolysis of hexacarbonyltungsten in acetonitrile.
reaction suitability
core: tungsten
reagent type: catalyst
storage
Air and thermally sensitive; pyrophoric. Use in a fume hood.
Tris(acetonitrile)tricarbonyltungstenSupplier
Shanghai Hanhong Scientific Co.,Ltd.
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
Sigma-Aldrich
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- 021-61415566 800-8193336
- orderCN@merckgroup.com
Shaanxi Dideu Medichem Co. Ltd
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- 029-029-81024372 17792795018
- 1027@dideu.com
Energy Chemical
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- 021-58432009 400-005-6266
- marketing1@energy-chemical.com
Pushan Industry (Shaanxi) Co., Ltd.
- Tel
- 029-81310890 13571859809
- info@pushanshiye.com