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Borane-2-picoline complex

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Borane-2-picoline complex Basic information

Product Name:
Borane-2-picoline complex
Synonyms:
  • 2-Methylpyridine borane complex
  • 2-Methylpyridine - borane (1:1)
  • Borane - 2-Picoline Complex 2-Picoline Borane 2-Methylpyridine Borane
  • orane-2-picoline coMplex
  • BORANE - 2-PICOLINE COMPLEX
  • 2-methylpyridine borane
  • 2-picoline borane
  • borane - 2-methylpyridine complex
CAS:
3999-38-0
MF:
C6H10BN
MW:
106.96
EINECS:
609-767-1
Product Categories:
  • B (Classes of Boron Compounds)
  • Boranes
  • Reduction
  • Synthetic Organic Chemistry
  • 3999-38-0
Mol File:
3999-38-0.mol
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Borane-2-picoline complex Chemical Properties

Melting point:
48 °C
Density 
1.297 g/mL at 25 °C
Flash point:
100°(212°F)
storage temp. 
2-8°C
solubility 
Dichloromethane (Sparingly), Ethyl Acetate (Slightly)
form 
Solid
color 
White
Water Solubility 
Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
Sensitive 
Moisture Sensitive
InChIKey
ZMASBEFBIXMNCP-UHFFFAOYSA-N
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Safety Information

Hazard Codes 
F,Xn,Xi
Risk Statements 
14/15-40-36/37/38-26
Safety Statements 
36/37-43-26-36/37/38-14/15
RIDADR 
UN 3130 6.1(4.3) / PGII
WGK Germany 
3
HazardClass 
4.3
PackingGroup 
II
HS Code 
29333990
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Borane-2-picoline complex Usage And Synthesis

Uses

Environmentally benign reducing agent. Reactant for: Reductive amination. N-Benzyl-protection of amino acid derivatives by reductive alkylation. Reductive alkoxyamination.

Uses

Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

General Description

2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.

Borane-2-picoline complexSupplier

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