Dicyclohexano-18-crown-6
Dicyclohexano-18-crown-6 Basic information
- Product Name:
- Dicyclohexano-18-crown-6
- Synonyms:
-
- cis-Dicyclohexano-18-crown-6, cis-syn-cis isomer, 98+%
- cis-Dicyclohexano-18-crown-6, mixture of syn-cis and anti-cis isomers, 98%
- d2-06
- Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, eicosahydro-
- Dicyclohexo-18-crown-6
- Eicosahydro-5,8,11,16,19,22-hexaoxadibenzo[a,j]cyclooctadecene
- Icosahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecine
- k)(1,4,7,10,13,16)hexaoxacyclooctadecin,eicosahydro-dibenzo(
- CAS:
- 16069-36-6
- MF:
- C20H36O6
- MW:
- 372.5
- EINECS:
- 240-216-4
- Product Categories:
-
- Crown Ethers
- Functional Materials
- Macrocycles for Host-Guest Chemistry
- Mol File:
- 16069-36-6.mol
Dicyclohexano-18-crown-6 Chemical Properties
- Melting point:
- 47-50 °C
- Boiling point:
- 344°C
- Density
- 1.102 g/cm
- refractive index
- 1.4909
- Flash point:
- 113 °C
- storage temp.
- Store below +30°C.
- form
- Crystalline Solid
- color
- White to slightly beige
- Water Solubility
- Slightly soluble
- Sensitive
- Hygroscopic
- Merck
- 14,2602
- BRN
- 1130529
- CAS DataBase Reference
- 16069-36-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Dicyclohexano-18-crown-6(16069-36-6)
- EPA Substance Registry System
- Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, eicosahydro- (16069-36-6)
Safety Information
- Hazard Codes
- T,Xn
- Risk Statements
- 23/24/25-36/37/38-20/21/22-36/38-22
- Safety Statements
- 26-36/37/39-45-38-28A-36
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- RTECS
- HP5385000
- F
- 3-9
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29329995
- Toxicity
- LD50 orally in Rabbit: 176 mg/kg
MSDS
- Language:English Provider:Perhydrodibenzo-18-crown-6
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Dicyclohexano-18-crown-6 Usage And Synthesis
Chemical Properties
White solid
Uses
Dicyclohexano is used as an anion activator and complexing agent which solubilizes alkali metal ions in non-polar solvents. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuffs etc,.
Uses
Anion activator, and complexing agent which solubilizes alkali metal ions in non-polar solvents.
Safety Profile
Poison by ingestion, skin contact, and intraperitoneal routes. An experimental teratogen. An eye and skin irritant. When heated to decomposition it emits acrid smoke and fumes.
Purification Methods
Purify it by chromatography on neutral alumina and eluting with an ether/hexane mixture [see Izatt et al. Inorg Chem 14 3132 1975]. Dissolve it in ether at ca 40o, and spectroscopic grade MeCN is added to the solution, which is then chilled. The crown ether precipitates and is filtered off. It is dried in vacuo at room temperature [Wallace J Phys Chem 89 1357 1985]. [V.gtle ed. Top Corr Chem (Host Guest Complex Chemistry) 98 1981.] SKIN IRRITANT.
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Dicyclohexano-18-crown-6(16069-36-6)Related Product Information
- Ethylcyclohexane
- Methylcyclohexane
- Cyclohexene oxide
- Cyclohexane
- 12-Crown-4
- 1,2-Cyclohexanediol
- 2-Ethoxyethyl ether
- 1-METHOXY-2-BUTANOL
- Triethylene glycol monoethyl ether
- 2-(2-HEXYLOXYETHOXY)ETHANOL
- 2-(PROPOXYETHOXY)ETHANOL
- TETRAETHYLENEGLYCOL MONOMETHYL ETHER
- Diethylene glycol monobutyl ether
- TRIETHYLENE GLYCOL MONOMETHYL ETHER
- Diethylene glycol monomethyl ether
- 4',4''(5'')-DI-TERT-BUTYLDICYCLOHEXANO-18-CROWN-6
- 2-(HEXYLOXY)ETHANOL
- PENTAETHYLENE GLYCOL MONOMETHYL ETHER