Basic information Reaction Safety Supplier Related
ChemicalBook >  Product Catalog >  Organic Chemistry >  Phosphines >  (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)

Basic information Reaction Safety Supplier Related

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Basic information

Product Name:
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
Synonyms:
  • 1-(diphenylphosphino)-2-(2-(diphenylphosphino)phenoxy)benzene
  • DPEPHOS [(Oxydi-2,1-phenylene)-bis-(diphenylphosphine)]
  • Bis(2-diphenylphosphinophenyl)ether, 99% DPEphos
  • Bis(2-diphenylphosphinophenl)ether
  • {2-[2-(diphenylphosphanyl)phenoxy]phenyl}diphenylphosphane
  • Bis(2-diphenylphosphinophenyl) ether 98% Min
  • Bis(2-diphenylphosphinophenyl)ether, 99% 25GR
  • Bis(2-diphenylphosphinophenyl)ether, 99% 5GR
CAS:
166330-10-5
MF:
C36H28OP2
MW:
538.55
EINECS:
678-206-0
Product Categories:
  • organophosphine ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
  • Pyridazines
  • Achiral Phosphine
  • Aryl Phosphine
Mol File:
166330-10-5.mol
More
Less

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Chemical Properties

Melting point:
184-187 °C (lit.)
Boiling point:
608.2±40.0 °C(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Crystalline Powder or Crystals
color 
White to off-white
BRN 
7729718
InChIKey
RYXZOQOZERSHHQ-UHFFFAOYSA-N
CAS DataBase Reference
166330-10-5(CAS DataBase Reference)
More
Less

Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090

MSDS

More
Less

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Usage And Synthesis

Reaction

  1. Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
  2. Has been recently applied to the C3 benzylation of indoles.
  3. Has been recently applied to the monoallylation of ammonia.
  4. Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
  5. Ligand used in carbonylation of aryl iodides.
  6. Ligand used in the direct C-H arylation of benzothiodiazoles.
  7. Ligand used in stereo-retentive azacyclization of propargylic carbonates.
  8. Ligand used in palladium catalyzed benzyne trimerization.

Chemical Properties

White to off-white crystalline powder or crystals

Uses

suzuki reaction

Uses

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

General Description

This product has been enhanced for catalytic efficiency.

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Preparation Products And Raw materials

Raw materials

Preparation Products

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)Supplier

Xinxiang Runyu Material Co., Ltd. Gold
Tel
166-166-37336996 15690792173
Email
chenxi.song@runvmat.com
Puyang Huicheng Electronic Material Co. Ltd. Gold
Tel
0393-0393-0393-8910800 15036113989
Email
info@huichengchem.com
BeiJing Greenchem Technology Co.,Ltd. Gold
Tel
131-21959385 15640741633
Email
chemrocking@bjgreenchem.com
Henan Research New Material Co., Ltd. Gold
Tel
1890-3931531 18903931628
Email
sales036@researchvip.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com