ChemicalBook > Product Catalog > Organic Chemistry > Phosphines > (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Basic information
- Product Name:
- (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
- Synonyms:
-
- 1-(diphenylphosphino)-2-(2-(diphenylphosphino)phenoxy)benzene
- DPEPHOS [(Oxydi-2,1-phenylene)-bis-(diphenylphosphine)]
- Bis(2-diphenylphosphinophenyl)ether, 99% DPEphos
- Bis(2-diphenylphosphinophenl)ether
- {2-[2-(diphenylphosphanyl)phenoxy]phenyl}diphenylphosphane
- Bis(2-diphenylphosphinophenyl) ether 98% Min
- Bis(2-diphenylphosphinophenyl)ether, 99% 25GR
- Bis(2-diphenylphosphinophenyl)ether, 99% 5GR
- CAS:
- 166330-10-5
- MF:
- C36H28OP2
- MW:
- 538.55
- EINECS:
- 678-206-0
- Product Categories:
-
- organophosphine ligand
- Phosphine Ligands
- Synthetic Organic Chemistry
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Polydentate Phosphine Ligands
- Pyridazines
- Achiral Phosphine
- Aryl Phosphine
- Mol File:
- 166330-10-5.mol
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(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Chemical Properties
- Melting point:
- 184-187 °C (lit.)
- Boiling point:
- 608.2±40.0 °C(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Crystalline Powder or Crystals
- color
- White to off-white
- BRN
- 7729718
- InChIKey
- RYXZOQOZERSHHQ-UHFFFAOYSA-N
- CAS DataBase Reference
- 166330-10-5(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 29319090
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Usage And Synthesis
Reaction
- Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
- Has been recently applied to the C3 benzylation of indoles.
- Has been recently applied to the monoallylation of ammonia.
- Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
- Ligand used in carbonylation of aryl iodides.
- Ligand used in the direct C-H arylation of benzothiodiazoles.
- Ligand used in stereo-retentive azacyclization of propargylic carbonates.
- Ligand used in palladium catalyzed benzyne trimerization.
Chemical Properties
White to off-white crystalline powder or crystals
Uses
suzuki reaction
Uses
Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
General Description
This product has been enhanced for catalytic efficiency.
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Preparation Products And Raw materials
Raw materials
EtanolEthyl acetateTetrahydrofurann-ButyllithiumDiphenyl oxideN,N,N',N'-TetramethylethylenediamineChlorodiphenylphosphine
Preparation Products
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)Supplier
Xinxiang Runyu Material Co., Ltd. Gold
- Tel
- 166-166-37336996 15690792173
- chenxi.song@runvmat.com
Puyang Huicheng Electronic Material Co. Ltd. Gold
- Tel
- 0393-0393-8910800 18236056670
- info@huichengchem.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Beijing Donghualituo Techonlogy Development Co.,Ltd.
- Tel
- 010-88425576
- sales@dhltchem.com
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(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)(166330-10-5)Related Product Information
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