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2-THIENYLZINC BROMIDE

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2-THIENYLZINC BROMIDE Basic information

Product Name:
2-THIENYLZINC BROMIDE
Synonyms:
  • 2-thienylzinc bromide solution
  • 2-THIENYLZINC BROMIDE
  • 2-THIENYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
  • 2-Thienylzine BroMide
  • 2-Thienylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
  • 2-Thienylzinc bromide solution 0.5M in THF
  • 2-Thienylzinc bromide, 0.5 M in THF
  • 2-Thienylzinc bromide solution 0.5 in THF
CAS:
45438-80-0
MF:
C4H3BrSZn
MW:
228.43
Product Categories:
  • Heteroaryl
  • Organozinc Halides
  • Reike and Organozinc Reagents
Mol File:
45438-80-0.mol
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2-THIENYLZINC BROMIDE Chemical Properties

Density 
0.973 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
InChI
1S/C4H3S.BrH.Zn/c1-2-4-5-3-1;;/h1-3H;1H;/q;;+1/p-1
InChIKey
KBBMRTYVFOYNIW-UHFFFAOYSA-M
SMILES
Br[Zn]c1cccs1
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Safety Information

Hazard Codes 
F,Xi,Xn
Risk Statements 
11-19-36/37-40
Safety Statements 
16-29-33-36/37-26
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
Storage Class
3 - Flammable liquids
Hazard Classifications
Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3

MSDS

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2-THIENYLZINC BROMIDE Usage And Synthesis

Uses

2-Thienylzinc bromide can be used as:

  • A starting material in the synthesis of heteroaryl sulfonamides by reacting with 2,4,6-trichlorophenyl chlorosulfate.
  • A substrate in the synthesis of naphthacenodithiophene derived polymers, which are used in transistor and solar cell devices.
  • An intermediate in the preparation of isoquinoline derived AICARFT inhibitors.

2-THIENYLZINC BROMIDESupplier

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