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Basic Green 1

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Basic Green 1 Basic information

Product Name:
Basic Green 1
Synonyms:
  • brilliantgreencrystalsh
  • brilliantgreendsc
  • brilliantgreeng
  • brilliantgreengx
  • brilliantgreenlake
  • brilliantgreenp
  • brilliantgreenspecial
  • ANILINE GREEN
CAS:
633-03-4
MF:
C27H34N2O4S
MW:
482.63
EINECS:
211-190-1
Product Categories:
  • Analytical Chemistry
  • Ion Association
  • Dyes and Pigments
  • Stains and Dyes
  • Triphenylmethane
  • AR
Mol File:
633-03-4.mol
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Basic Green 1 Chemical Properties

Melting point:
210 °C (dec.)(lit.)
Boiling point:
100.0
Density 
1.1016 (rough estimate)
vapor density 
16.6 (vs air)
vapor pressure 
0Pa at 25℃
refractive index 
1.6510 (estimate)
storage temp. 
room temp
solubility 
100g/l
form 
Powder/Solid
Colour Index 
42040
color 
Metallic green
PH Range
Yellow (0.0) to green (2.6)
Odor
Odorless
PH
2.5 (10g/l, H2O, 25℃)
Water Solubility 
100 G/L (25 ºC)
λmax
625nm, 428nm
Merck 
14,1374
BRN 
3901207
Stability:
Stable. Incompatible with strong oxidizing agents, reducing agents.
Biological Applications
Antimalarial agent; detecting carious tissue; treating anococcygeal pain syn- drome; wound dressing materials; catheter; mouthwash
Major Application
Black matrix, color filter, photoresists, sensors, inks, rodenticide, dyes, cosmetics, detecting dental carious tissue, Escherichia coli, antimalarial agent, dressing material, treatment of cancer, medical devices
InChIKey
UURSSPGMJADCAU-UHFFFAOYSA-N
LogP
0.765 at 20℃
CAS DataBase Reference
633-03-4(CAS DataBase Reference)
EPA Substance Registry System
C.I. Basic Green 1 (633-03-4)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-36-36/37/38-20/21/22
Safety Statements 
26-39-36-24/25
RIDADR 
2811
WGK Germany 
3
RTECS 
BP6825000
10-21
TSCA 
Yes
HS Code 
3204 13 00
HazardClass 
6.1(a)
PackingGroup 
II
Hazardous Substances Data
633-03-4(Hazardous Substances Data)
Toxicity
LD100 i.v. in mice: 3 mg/kg (Anderson)

MSDS

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Basic Green 1 Usage And Synthesis

Description

C.I. Basic Green 1 is a metallic green, odorlesscrystal or powder. Molecular weight =482.69; Meltingpoint =210℃. Soluble in water.

Chemical Properties

metallic green crystals

Chemical Properties

C.I. Basic Green 1 is a metallic green, odorless crystal or powder

Uses

Dyeing silk, wool, leather, jute and cotton yellowish-green; manufacture of green ink; biological stain; indicator.

Uses

Brilliant Green a stain used in bacteriological media.

Preparation

in the presence of sulfuric acid hydrochloric acid or, Benzaldehyde?and N,N-diethylbenzenamine condensation, and then will product oxidation, and translated into sulfate. The first generation of resin mixture will suddenly for curing crystalline good crystals.

Definition

ChEBI: An organic hydrogensulfate salt having 4-{[4-(diethylamino)phenyl](phenyl)methylidene}-N,N-diethylcyclohexa-2,5-dien-1-iminium as the counterion.

General Description

Brilliant green is a triphenylmethane dye, found to be toxic to humans and animals. It is widely used in dying wool, leather, silk, jute, and cotton. It is also used in the manufacturing of green ink, as a staining constituent of bacteriological media.

Flammability and Explosibility

Non flammable

Biochem/physiol Actions

Brilliant Green is a dye and an antiseptic agent.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. A rmld human skin irritant. Mutation data reported. See also ALDEHYDES and SULFATES. When heated to decomposition it emits very toxic fumes of NOx, NH3, and SOx.

Potential Exposure

C.I. Basic Green 1 is used in dyeing silk, wool, leather, jute, and cotton yellowish-green; manufacturing green ink; as staining constituent of bacteriological media; indicator, an intestinal anthelmintic; a C.I. Basic Green 1 861 wound antiseptic; treatment of mycotic infections; agricultural fungicide (Not registered as a pesticide in the United States).

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for atleast 15 min, occasionally lifting upper and lower lids.Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and washimmediately with soap and water. Seek medical attentionimmediately. If this chemical has been inhaled, removefrom exposure, begin rescue breathing (using universalprecautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make anunconscious person vomit.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location

Shipping

UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

Purify the dye by precipitating the perchlorate from aqueous solution (0.3%) after filtering, heating to 75o and adjusting to pH 1-2. Recrystallise it from EtOH/water (1:4) [Kerr & Gregory Analyst (London) 94 1036 1969]. [Beilstein 13 IV 2281.]

Properties and Applications

bright green. Green flash golden sand shape. Slightly soluble in cold water, in 98 ℃ of hot water dissolves only 8 g/L, soluble in ethanol to blue. The strong sulfuric acid for yellow green, diluted into blue; For orange in nitric acid. The dye solution for blue purple, add sodium hydroxide have dark purple precipitation; Join the hydrochloric acid become green light yellow. Used for silk, wool, acrylic, tannin mordant dyeing cotton cloth dyeing. Also used in leather, hemp, paper, wood, bamboo or color, also used in the manufacture of paint, medicine used for disinfectant.

Standard Light Fastness Persperation Fastness Ironing Fastness Soaping
Fading Stain Fading Stain Fading Stain
ISO 4 4 4-5 4 4-5
AATCC 2-3

Incompatibilities

Oxidizing agents, reducing agents; anionics, and aqueous solutions of bentonite. Keep away from moisture

Basic Green 1 Preparation Products And Raw materials

Raw materials

Basic Green 1Supplier

Anhui Royal Chemical Co., Ltd. Gold
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25-86655873 13962173137
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marketing@royal-chem.com
Yancheng Green Chemicals Co.,Ltd. Gold
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25-25-86655873 02586655873
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Hubei Chenghai Chemical Co., Ltd Gold
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027-59220433 18327245847
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Email
market03@meryer.com