2,2-Bis[4-(4-aminophenoxy)phenyl]propane
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Basic information
- Product Name:
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Synonyms:
-
- 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline
- 2,2'-Di-[4-(4-aminophenyloxy)phenyl]-propane
- 4,4'-(4,4'-Isopropyl
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propan
- 2,2-Bis[p-(4-aMinophenoxy)phenyl]propane
- 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 98%
- 4,4'-(4,4'-isopropylidenediphenyl-1,1'-diyldioxy),BAPP
- 4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bis-benzenamin
- CAS:
- 13080-86-9
- MF:
- C27H26N2O2
- MW:
- 410.51
- EINECS:
- 235-985-8
- Product Categories:
-
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
- API
- Organics
- Miscellaneous
- Bisphenol A type Compounds (for High-Performance Polymer Research)
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis
- Functional Materials
- Reagent for High-Performance Polymer Research
- 13080-86-9
- Mol File:
- 13080-86-9.mol
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties
- Melting point:
- 127-130 °C(lit.)
- Boiling point:
- 587.1±50.0 °C(Predicted)
- Density
- 1.178±0.06 g/cm3(Predicted)
- vapor pressure
- 0-0Pa at 20-25℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 5.16±0.10(Predicted)
- form
- Solid:particulate/powder
- Water Solubility
- Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO).
- InChI
- InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3
- InChIKey
- KMKWGXGSGPYISJ-UHFFFAOYSA-N
- SMILES
- C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C
- LogP
- 4.3-4.9 at 35℃ and pH7
- CAS DataBase Reference
- 13080-86-9(CAS DataBase Reference)
- EPA Substance Registry System
- Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9)
Safety Information
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- RTECS
- CY1062500
- TSCA
- Yes
- HS Code
- 29222990
MSDS
- Language:English Provider:SigmaAldrich
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Usage And Synthesis
Description
2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.
Chemical Properties
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid
Uses
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.
Uses
It is applied in pharmaceutical industry.
Application
2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites.
Synthesis
2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction[1].
References
[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086.
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2,2-Bis[4-(4-aminophenoxy)phenyl]propane(13080-86-9)Related Product Information
- Phenyltriethoxysilane
- 4-Aminobenzoic acid
- 4-Amino-benzenesulfonic acid monosodium salt
- Diphenyl ether
- 2,2-Dimethoxypropane
- Trimethoxyphenylsilane
- PHENYL VALERATE
- Phenyl salicylate
- Propane
- PHENYL RESIN
- Phenylacetic acid
- Bisphenol A
- 4-CUMYLPHENOL
- 4-AMINO-4'-TERT BUTYL DIPHENYL ETHER
- 4-AMINO-4'-METHYLDIPHENYL ETHER
- 4-Phenoxyaniline
- Bis[4-(4-aminophenoxy)phenyl]sulfone
- Diphenyl sulfone