2,4-DICHLORO-6-MORPHOLINO-1,3,5-TRIAZINE Chemical Properties

Melting point:

137 °C

Boiling point:

441.9±55.0 °C(Predicted)

Density 

1.503±0.06 g/cm3(Predicted)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

form 

powder to crystal

pka

1.01±0.10(Predicted)

color 

White to Almost white

InChI

InChI=1S/C7H8Cl2N4O/c8-5-10-6(9)12-7(11-5)13-1-3-14-4-2-13/h1-4H2

InChIKey

UQAMDAUJTXFNAD-UHFFFAOYSA-N

SMILES

N1=C(N2CCOCC2)N=C(Cl)N=C1Cl

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

22-37/38-41

Safety Statements 

26-39

HS Code 

2934.99.4400

2,4-DICHLORO-6-MORPHOLINO-1,3,5-TRIAZINE Usage And Synthesis

Synthesis

The general procedure for the synthesis of 2,4-dichloro-6-morpholino-1,3,5-triazine from morpholine was as follows: to a solution of cyanuric acid (230.5 g, 1,250 mmol) in acetone (2.25 L) was slowly added dropwise at 5°C morpholine (98.0 g, 1,125 mmol) and triethylamine (113.0 g, 1,125 mmol) in acetone (2.25 L) solution. After completion of the reaction, the resulting mixture was poured into water to precipitate the product. The white precipitate was collected by filtration and washed with methanol to give final white crystals 2,4-dichloro-6-morpholino-1,3,5-triazine (231.9 g, 986.9 mmol) in 88% yield. The mass spectrum (MS) of the product showed m/z: 234 (M+) and the nuclear magnetic resonance hydrogen spectrum (1H-NMR, CDCl3) showed δ: 3.75 (4H, triple peak, J=4Hz), 3.87 (4H, triple peak, J=4Hz).

References

[1] Patent: US2007/244110, 2007, A1. Location in patent: Page/Page column 4

2,4-DICHLORO-6-MORPHOLINO-1,3,5-TRIAZINE(6601-22-5)Related Product Information

• Dichloroethane
• 2,3-Dichloropyridine-4-carboxaldehyde
• 2,4-Dichloropyridine-3-carboxylic acid
• 2,3,5-Trichloropyridine-4-carboxylic acid
• 2,4-Dichloropyridine
• 2,3-dichloro-4-pyridineboronic acid
• 2,3-Dichloropyridine
• 2,4-Dichloro-3-iodopyridine
• 2,3-DICHLOROPYRIDINE-4-CARBOXYLIC ACID
• 2,3,5-Trichloropyridine-4-carboxaldehyde
• 2,5-Dichloro-4-iodopyridine
• 2,4-BIS(BENZYLOXY)PYRIMIDINE-5-BORONIC ACID
• Butafosfan
• 1,3,5-Triazine
• Poly[N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexanediamine-co-2,4-dichloro-6-morpholino-1,3,5-triazine]
• 2,4-DICHLORO-6-MORPHOLINO-1,3,5-TRIAZINE
• 2-(N,N-DIETHYLAMINO)-4,6-DICHLOROTRIAZINE
• Etatryn