Rhodiumtriphenylacetate Chemical Properties

Melting point:

260-263°C

storage temp. 

Inert atmosphere,Room Temperature

form 

powder to crystal

color 

Green to Dark green

InChI

InChI=1S/3C20H16O2.Rh/c3*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h3*1-15H,(H,21,22);/q;;;+3/p-3

InChIKey

LJIVYHNRWSWCRU-UHFFFAOYSA-K

SMILES

[Rh+3].C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.C([O-])(=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

Safety Information

Hazard Codes 

Xn

Risk Statements 

40

Safety Statements 

23-24/25-36/37

WGK Germany 

2

HS Code 

2931.90.6000

Rhodiumtriphenylacetate Usage And Synthesis

Uses

Catalyst for:

• Amination of allene carbamates
• Allene aziridination to stereoselectively prepare cyclic cabamates
• C-H bond nitrene insertion
• Enantioselective cyclopropanation
• Preparation of cyclic oxonium ylides

reaction suitability

core: rhodium
reagent type: catalyst
reaction type: C-H Activation

Rhodiumtriphenylacetate(142214-04-8)Related Product Information

• 1,10-Phenanthroline hydrate
• CARDIO-SPECT
• ZIRCONIUM TRIFLUOROACETYLACETONATE
• Tetrakis(1,1,1,3,3,3-hexafluoroisopropyl) Orthosilicate
• Rhodium
• Rhodium(III) sulfate
• Rhodanine
• Rhodium(III) Chloride
• Rhodanine-3-acetic acid
• Rhodium(II) acetate dimer
• TETRAKIS(TRIPHENYLACETATO)DIRHODIUM(II)