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1,4-Butanediol diglycidyl ether

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1,4-Butanediol diglycidyl ether Basic information

Product Name:
1,4-Butanediol diglycidyl ether
Synonyms:
  • 1,4-Butanediol diglycidyl ether >=95%
  • 1,4-Butanediol diglycidyl ether technical grade, 60%
  • 1,4-Butanediol diglycidyl ether, 98%, 98%
  • 1,4-butandedioldiglycidylether
  • 1,4-Butane diglycidyl ether
  • 1,4-butanediglycidylether
  • 1,4-Diglycidloxybutane
  • 2-([4-(2-Oxiranylmethoxy)butoxy]methyl)oxirane
CAS:
2425-79-8
MF:
C10H18O4
MW:
202.25
EINECS:
219-371-7
Product Categories:
  • Epoxy Diluents
  • Epoxide Monomers
  • Oxiranes
  • Simple 3-Membered Ring Compounds
  • Monomers
  • Polymer Science
  • bc0001
  • 2425-79-8
Mol File:
2425-79-8.mol
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1,4-Butanediol diglycidyl ether Chemical Properties

Melting point:
-21 °C
Boiling point:
266 °C (lit.)
Density 
1.1 g/mL at 25 °C (lit.)
vapor pressure 
~10 mm Hg ( 20 °C)
refractive index 
n20/D 1.453
Flash point:
>230 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
Liquid
Specific Gravity
1.07
color 
Clear yellow
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
BRN 
115238
Stability:
Hygroscopic
InChIKey
SHKUUQIDMUMQQK-UHFFFAOYSA-N
LogP
-0.27 at 25℃
CAS DataBase Reference
2425-79-8(CAS DataBase Reference)
NIST Chemistry Reference
Oxirane, 2,2'-[1,4-butanediylbis(oxymethylene)]bis-(2425-79-8)
EPA Substance Registry System
1,4-Butanediol diglycidyl ether (2425-79-8)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21-36/38-43-52/53-22
Safety Statements 
26-28-37/39-28B
WGK Germany 
1
RTECS 
EJ5100000
3-10
TSCA 
Yes
HS Code 
29109000
Hazardous Substances Data
2425-79-8(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 1134mg/kg

MSDS

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1,4-Butanediol diglycidyl ether Usage And Synthesis

Description

1,4-Butanediol diglycidyl ether is a reactive diluent in epoxy resins.

Chemical Properties

Clear yellow liquid

Uses

1,4-Butanediol diglycidyl ether is used for preparing amylose, xylan and hydroxyethyl-cellulose, to cross link polyethylenimine which also serves as a hole-blocking layer in organic solar cells, to cross link hyaluronic acid into hydrogels and for the activation of soluble dextran polymers. It is the most commonly used homobifunctional epoxide compound

Uses

Production Methods

The compound results from condensation of butanediol with epichlorohydrin followed by dehydrochlorination with caustic.

General Description

Clear pale yellow liquid.

Air & Water Reactions

Hygroscopic. Water soluble

Reactivity Profile

1,4-Butanediol diglycidyl ether reacts with acids.

Fire Hazard

1,4-Butanediol diglycidyl ether is combustible.

Flammability and Explosibility

Non flammable

Contact allergens

This substance is a reactive diluent in epoxy resins

Carcinogenicity

A2 year dermal cancer bioassay was conducted in CF1 mice at doses of 0%, 0.05%, and 0.2% in acetone . Treatment did not adversely affect survival, did not increase the incidence of skin tumors, and did not result in significant skin irritation. There were no statistically significant increases in incidence of any systemic tumors, except for lymphatic tumors in females. Because there was a high background incidence of this tumor type in CF1 mice used in the testing laboratory , there was no clear evidence of 1,4-BDDGE-induced carcinogenicity.

1,4-Butanediol diglycidyl etherSupplier

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