1,3-Bis(diphenylphosphino)propane Chemical Properties

Melting point:

63-65 °C (lit.)

Boiling point:

529.7±33.0 °C(Predicted)

Flash point:

235°C

storage temp. 

Inert atmosphere,Room Temperature

form 

Granules or Powder

color 

White to light yellow-beige

Water Solubility 

insoluble

Sensitive 

Air Sensitive

BRN 

2821785

InChI

InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2

InChIKey

LVEYOSJUKRVCCF-UHFFFAOYSA-N

SMILES

P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1

CAS DataBase Reference

6737-42-4(CAS DataBase Reference)

NIST Chemistry Reference

1,3-Bis(diphenylphosphino)propane(6737-42-4)

EPA Substance Registry System

Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39-36

WGK Germany 

3

F 

10-23

TSCA 

Yes

HS Code 

29310095

MSDS

• Language:English Provider:1,3-Bis(diphenylphosphino)propane
• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

1,3-Bis(diphenylphosphino)propane Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

1,3-Bis(diphenylphosphino)propane(6737-42-4)Related Product Information

• BIS-Tris Propane
• Di(trimethylol propane)
• Diphenylmethane
• tert-Butylchlorodiphenylsilane
• N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
• Diphenylsilane
• Chlorodiphenylphosphine
• Diphenylphosphine
• 1,1'-Bis(diphenylphosphino)ferrocene
• 1,2-Bis(diphenylphosphino)ethane
• 1,4-Bis(diphenylphosphino)butane
• Propane
• DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)
• (2R,4R)-(+)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE
• (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE
• [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
• 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE
• TRIMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE)