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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Basic information

Product Name:
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms:
  • TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
  • (E)-1,2-Bis(diphenylphosphino)ethene
  • [(E)-1,2-Ethenediyl]bis(diphenylphosphine)
  • [(E)-Ethene-1,2-diyl]bis(diphenylphosphine)
  • [(E)-Vinylene]bis(diphenylphosphine)
  • trans-vinylenebis[diphenylphosphine]
  • trans-1,2-Bis(diphenylphosphino)ethylene,97%
  • NSC 132587
CAS:
983-81-3
MF:
C26H22P2
MW:
396.4
EINECS:
213-570-2
Product Categories:
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
Mol File:
983-81-3.mol
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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties

Melting point:
126-130 °C(lit.)
Boiling point:
546.8±33.0 °C(Predicted)
form 
Crystalline
color 
White to Almost white
Sensitive 
Air Sensitive
BRN 
757793
CAS DataBase Reference
983-81-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 3464 6.1/PG 2
WGK Germany 
3
HS Code 
29310099

MSDS

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TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENESupplier

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