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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic rhodium >  Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Basic information

Product Name:
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms:
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • (R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II)
  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
  • Ru-BINAP
  • RU(OAC)2[(R)-BINAP]
  • Ru(OAc)2[(R)-binap]
  • -binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].
  • (OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium
CAS:
325146-81-4
MF:
C48H40O4P2Ru
MW:
843.86
Product Categories:
  • Ru
Mol File:
325146-81-4.mol
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
ocher to green
Sensitive 
air sensitive
InChI
InChI=1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);
InChIKey
XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES
CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1
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Safety Information

WGK Germany 
3
HS Code 
28439000
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Usage And Synthesis

Reaction

  1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.
  2. Catalyst used in the synthesis of β-amino acids by hydrogenation.

Chemical Properties

Light yellow powder

Uses

(R)-Ru(OAc)2(BINAP) is a catalyst.

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)Supplier

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