Dichlorotriphenyl bismuth
Dichlorotriphenyl bismuth Basic information
- Product Name:
- Dichlorotriphenyl bismuth
- Synonyms:
-
- DICHLOROTRIPHENYLBISMUTH
- TRIPHENYLBISMUTH(V) DICHLORIDE
- TTIPHENYLBISMUTH DICHLORIDE
- TRIPHENYLBISMUTH DICHLORIDE
- Triphenylbismuthine dichloride
- dichloro(triphenyl)bismuthorane
- Dichlorotriphenylbismuth(V)
- Dichlorotriphenylbismuthine
- CAS:
- 594-30-9
- MF:
- C18H15BiCl2
- MW:
- 511.2
- Product Categories:
-
- Semimetal Compounds
- Synthetic Organic Chemistry
- Bi (Bismuth) Compounds
- Classes of Metal Compounds
- Hypervalent Bismuth Compounds
- Mol File:
- 594-30-9.mol
Dichlorotriphenyl bismuth Chemical Properties
- Melting point:
- 128-142°C
- storage temp.
- Refrigerator
- solubility
- soluble in Tetrahydrofuran
- form
- powder to crystal
- color
- White to Almost white
- EPA Substance Registry System
- Triphenylbismuthine dichloride (594-30-9)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39
- HS Code
- 2931.90.6000
Dichlorotriphenyl bismuth Usage And Synthesis
Uses
Dichlorotriphenyl bismuth is used for phenylation of phenols, ketones and enols, and nitro compounds.
Preparation
Dichlorotriphenyl bismuth is easily prepared by oxidation of Triphenylbismuthine either by bubbling Chlorine gas into an ethereal solution of Ph3Bi at 0°C, or by addition of 1 equiv of Sulfuryl Chloride to a solution of Ph3Bi in CH2Cl2 at -78°C. The action of Phenyllithium on Ph3BiCl2 leads to pentaphenylbismuth (mp 77-78 °C). Addition of 1 equiv of a carboxylic or sulfonic acid to Ph5Bi affords compounds of the type Ph4BiX.(Ph4BiOCOCF3: mp 120-132 °C; Ph4BiOTs: mp 155-162 °C).
Definition
ChEBI: Dichloro(triphenyl)bismuthorane is an organobismuth compound. It derives from a hydride of a bismuthorane.
storage
Dichlorotriphenyl bismuth is a stable white solid; can be stored in the refrigerator in the absence of moisture.
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Dichlorotriphenyl bismuth(594-30-9)Related Product Information
- Bismuth
- Cobalt chloride
- 2,3,5-Triphenyltetrazolium chloride
- Bismuth trioxide
- DICHLOROTRIPHENYLPHOSPHORANE
- Chlorodiphenylphosphine
- Triphenylphosphine
- Bismuth trichloride
- Triphenylbismuth Difluoride
- TRIPHENYLBISMUTH CARBONATE
- BIS(ACETATO-O)TRIPHENYLBISMUTH
- Benzyltriphenylphosphonium chloride
- Triphenylbismuth
- BISMUTH TRIMETHYL
- DICHLORO(TRI-O-TOLYL)BISMUTH
- DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH
- DICHLOROTRIS(4-TRIFLUOROMETHYLPHENYL)BISMUTH
- Dichlorotriphenyl bismuth