1-ETHYLPIPERIDINE HYPOPHOSPHITE Chemical Properties

Melting point:

40-43 °C (lit.)

Flash point:

133 °F

storage temp. 

2-8°C

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22-36/37/38

Safety Statements 

26-36

RIDADR 

UN 1325 4.1/PG 2

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

1-ETHYLPIPERIDINE HYPOPHOSPHITE Usage And Synthesis

Uses

Reagent for:
Synthesis of spiroketals via intramolecular iodoetherification
A facile radical cyclization diverted to a rearrangement-cyclization with base
Radical deoxygenation
Synthesis of allylic H-phosphinates

General Description

1-Ethylpiperidine hypophosphite promotes the carbon-carbon bond forming radical reactions in both aqueous and organic media. EPHP plays an important role of a good chain carrier during the radical addition of gem-dihalocompounds to electron-deficient olefins. It has been reported as a suitable radical reducing agent for organic halides.

1-ETHYLPIPERIDINE HYPOPHOSPHITE(145060-63-5)Related Product Information

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• 1-ETHYLPIPERIDINE HYPOPHOSPHITE
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