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(1E)-1-Iodo-1-hexene

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(1E)-1-Iodo-1-hexene Basic information

Product Name:
(1E)-1-Iodo-1-hexene
Synonyms:
  • (1E)-1-Iodo-1-hexene
  • (E)-1-Hexenyl iodide
  • (E)-1-Iodo-1-hexene
  • trans-1-Iodo-1-hexene
  • 1(E)-Iodo-hex-1-ene
  • 1-Hexene, 1-iodo-, (1E)-
  • 1-iodohex-1-ene
  • (1E)-1-Iodo-1-hexene ISO 9001:2015 REACH
CAS:
16644-98-7
MF:
C6H11I
MW:
210.06
Product Categories:
  • Acyclic
  • Alkenes
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
Mol File:
16644-98-7.mol
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(1E)-1-Iodo-1-hexene Chemical Properties

Boiling point:
151.64°C (estimate)
Density 
1.4517 (rough estimate)
refractive index 
n20/D 1.509
BRN 
1840329
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
22-51/53
Safety Statements 
61
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
3
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(1E)-1-Iodo-1-hexene Usage And Synthesis

Uses

Palladium-catalyzed carboalkoxylation gives appreciable stereospecific vinylic halides, including trans-1-Iodohexene. Also, trans-1-Iodohexene cross coupled with (E)??- or (Z)??-??vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry

Synthesis Reference(s)

Tetrahedron Letters, 15, p. 543, 1974 DOI: 10.1016/S0040-4039(01)82266-8
The Journal of Organic Chemistry, 54, p. 6064, 1989 DOI: 10.1021/jo00287a017

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