ChemicalBook > Product Catalog > Organic Chemistry > Hydrocarbons and derivatives > Acyclic hydrocarbons > (1E)-1-Iodo-1-hexene
(1E)-1-Iodo-1-hexene
(1E)-1-Iodo-1-hexene Basic information
- Product Name:
- (1E)-1-Iodo-1-hexene
- Synonyms:
-
- (1E)-1-Iodo-1-hexene
- (E)-1-Hexenyl iodide
- (E)-1-Iodo-1-hexene
- trans-1-Iodo-1-hexene
- 1(E)-Iodo-hex-1-ene
- 1-Hexene, 1-iodo-, (1E)-
- 1-iodohex-1-ene
- (1E)-1-Iodo-1-hexene ISO 9001:2015 REACH
- CAS:
- 16644-98-7
- MF:
- C6H11I
- MW:
- 210.06
- Product Categories:
-
- Acyclic
- Alkenes
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Mol File:
- 16644-98-7.mol
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(1E)-1-Iodo-1-hexene Chemical Properties
- Boiling point:
- 151.64°C (estimate)
- Density
- 1.4517 (rough estimate)
- refractive index
- n20/D 1.509
- BRN
- 1840329
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(1E)-1-Iodo-1-hexene Usage And Synthesis
Uses
Palladium-catalyzed carboalkoxylation gives appreciable stereospecific vinylic halides, including trans-1-Iodohexene. Also, trans-1-Iodohexene cross coupled with (E)??- or (Z)??-??vinylstannanes gives good yields of stereoisomerically pure unsymmetrical dienes with the same double bond geometry
Synthesis Reference(s)
Tetrahedron Letters, 15, p. 543, 1974 DOI: 10.1016/S0040-4039(01)82266-8
The Journal of Organic Chemistry, 54, p. 6064, 1989 DOI: 10.1021/jo00287a017
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