ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organomagnesium > METHYLMAGNESIUM IODIDE
METHYLMAGNESIUM IODIDE
METHYLMAGNESIUM IODIDE Basic information
- Product Name:
- METHYLMAGNESIUM IODIDE
- Synonyms:
-
- METHYLMAGNESIUM IODIDE
- MAGNESIUM METHYL IODIDE
- iodomethyl-magnesiu
- methylmagnesiumiodidesol.
- Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
- Methylmagnesium iodide solution
- iodomethylmagnesium
- METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER
- CAS:
- 917-64-6
- MF:
- CH3IMg
- MW:
- 166.24
- EINECS:
- 213-031-1
- Product Categories:
-
- Grignard Reagent
- Alkyl
- Chemical Synthesis
- Organic Bases
- Organometallic Reagents
- Synthetic Reagents
- Classes of Metal Compounds
- Grignard Reagents
- Grignard Reagents & Alkyl Metals
- AlkylChemical Synthesis
- Grignard Reagents
- Organic Bases
- Organometallic Reagents
- Synthetic Reagents
- Mg (Magnesium) Compounds
- Synthetic Organic Chemistry
- Typical Metal Compounds
- Mol File:
- 917-64-6.mol
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METHYLMAGNESIUM IODIDE Chemical Properties
- Density
- 1.26 g/mL at 20 °C
- Flash point:
- -40 °C
- BRN
- 1209226
- InChIKey
- AUPXBVDHVRZMIB-UHFFFAOYSA-M
- EPA Substance Registry System
- Magnesium, iodomethyl- (917-64-6)
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Safety Information
- Hazard Codes
- F+,C,F
- Risk Statements
- 12-14/15-22-34-66-67-19-11
- Safety Statements
- 16-26-36/37/39-43-45-7/8
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 1-3-10
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
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METHYLMAGNESIUM IODIDE Usage And Synthesis
Chemical Properties
Dark grey liquid
Uses
Alkylating agent in organic synthesis, Grignardreagent.
Uses
Methylmagnesium iodide solution can be used:
- To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
- In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
- To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
- In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.
Definition
Available as solution inether.
Hazard
Flammable, dangerous fire and explosionrisk.
METHYLMAGNESIUM IODIDESupplier
Lianyungang Jiezhong Pharmaceutical Technology Co., Ltd Gold
- Tel
- 13165449089
- 2124455948@qq.com
Nanjing Habo Medical Technology Co., Ltd. Gold
- Tel
- 025-85760892 13376090521
- sales@habotech.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Beijing Donghualituo Techonlogy Development Co.,Ltd.
- Tel
- 010-88425576
- sales@dhltchem.com
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METHYLMAGNESIUM IODIDE(917-64-6)Related Product Information
- PHENYLMAGNESIUM IODIDE
- ethylmagnesium iodide
- ISOPROPYLMAGNESIUM BROMIDE
- Vinylmagnesium chloride
- TERT-BUTYLMAGNESIUM CHLORIDE
- Methylmagnesium Bromide
- ISOBUTYLMAGNESIUM CHLORIDE
- ISOBUTYLMAGNESIUM BROMIDE
- N-BUTYLMAGNESIUM BROMIDE
- Butylmagnesium chloride
- PHENYLMAGNESIUM BROMIDE
- ALLYLMAGNESIUM BROMIDE
- Deuterated methyl magnesium iodide
- Magnesium
- METHYLMAGNESIUM IODIDE
- trideutero-methylmagnesium iodide
- 3-THIENYLMAGNESIUM IODIDE
- 3-CHLORO-4-METHYLPHENYLMAGNESIUM IODIDE