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METHYLMAGNESIUM IODIDE

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METHYLMAGNESIUM IODIDE Basic information

Product Name:
METHYLMAGNESIUM IODIDE
Synonyms:
  • METHYLMAGNESIUM IODIDE
  • MAGNESIUM METHYL IODIDE
  • iodomethyl-magnesiu
  • methylmagnesiumiodidesol.
  • Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
  • Methylmagnesium iodide solution
  • iodomethylmagnesium
  • METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER
CAS:
917-64-6
MF:
CH3IMg
MW:
166.24
EINECS:
213-031-1
Product Categories:
  • Grignard Reagent
  • Alkyl
  • Chemical Synthesis
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • Classes of Metal Compounds
  • Grignard Reagents
  • Grignard Reagents & Alkyl Metals
  • AlkylChemical Synthesis
  • Grignard Reagents
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
Mol File:
917-64-6.mol
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METHYLMAGNESIUM IODIDE Chemical Properties

Density 
1.26 g/mL at 20 °C
Flash point:
-40 °C
BRN 
1209226
InChIKey
AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System
Magnesium, iodomethyl- (917-64-6)
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Safety Information

Hazard Codes 
F+,C,F
Risk Statements 
12-14/15-22-34-66-67-19-11
Safety Statements 
16-26-36/37/39-43-45-7/8
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
1-3-10
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090

MSDS

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METHYLMAGNESIUM IODIDE Usage And Synthesis

Chemical Properties

Dark grey liquid

Uses

Alkylating agent in organic synthesis, Grignardreagent.

Uses

Methylmagnesium iodide solution can be used:

  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

METHYLMAGNESIUM IODIDESupplier

Lianyungang Jiezhong Pharmaceutical Technology Co., Ltd Gold
Tel
13165449089
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2124455948@qq.com
Nanjing Habo Medical Technology Co., Ltd. Gold
Tel
025-85760892 13376090521
Email
sales@habotech.com
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
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market03@meryer.com
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Email
sales@dhltchem.com