METHYLMAGNESIUM IODIDE CAS#: 917-64-6

ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organomagnesium > METHYLMAGNESIUM IODIDE

METHYLMAGNESIUM IODIDE

Basic information Safety Supplier Related

METHYLMAGNESIUM IODIDE Basic information

Product Name:

METHYLMAGNESIUM IODIDE

Synonyms:

METHYLMAGNESIUM IODIDE
MAGNESIUM METHYL IODIDE
iodomethyl-magnesiu
methylmagnesiumiodidesol.
Methylmagnesium Iodide (33% in Ethyl Ether, ca. 2mol/L)
Methylmagnesium iodide solution
iodomethylmagnesium
METHYLMAGNESIUM IODIDE SOL., ~3 M IN DIE THYL ETHER

CAS:

917-64-6

MF:

CH3IMg

MW:

166.24

EINECS:

213-031-1

Product Categories:

Grignard Reagent
Alkyl
Chemical Synthesis
Organic Bases
Organometallic Reagents
Synthetic Reagents
Classes of Metal Compounds
Grignard Reagents
Grignard Reagents & Alkyl Metals
AlkylChemical Synthesis
Grignard Reagents
Organic Bases
Organometallic Reagents
Synthetic Reagents
Mg (Magnesium) Compounds
Synthetic Organic Chemistry
Typical Metal Compounds

Mol File:

917-64-6.mol

Less

METHYLMAGNESIUM IODIDE Chemical Properties

Density: 1.26 g/mL at 20 °C
Flash point:: -40 °C
BRN: 1209226
InChIKey: AUPXBVDHVRZMIB-UHFFFAOYSA-M
EPA Substance Registry System: Magnesium, iodomethyl- (917-64-6)

Less

Safety Information

Hazard Codes: F+,C,F
Risk Statements: 12-14/15-22-34-66-67-19-11
Safety Statements: 16-26-36/37/39-43-45-7/8
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10
HazardClass: 4.2
PackingGroup: I
HS Code: 29319090

MSDS

Language:English Provider:SigmaAldrich

Less

METHYLMAGNESIUM IODIDE Usage And Synthesis

Chemical Properties

Dark grey liquid

Uses

Alkylating agent in organic synthesis, Grignardreagent.

Uses

Methylmagnesium iodide solution can be used:

To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.
In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.
To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.
In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.

Definition

Available as solution inether.

Hazard

Flammable, dangerous fire and explosionrisk.

METHYLMAGNESIUM IODIDESupplier

Lianyungang Jiezhong Pharmaceutical Technology Co., Ltd Gold

Tel: 13165449089
Email: 2124455948@qq.com

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Email: jkinfo@jkchemical.com

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Email: market03@meryer.com

Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Email: sales@dhltchem.com

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Email: sales@demochem.com

Less