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(S)-(+)-2-Butanol

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(S)-(+)-2-Butanol Basic information

Product Name:
(S)-(+)-2-Butanol
Synonyms:
  • (S)-(+)-2-BUTANOL 99%
  • (2S)-Butanol
  • (S)-(+)-2-Butanol ChiPros(R), produced
  • D-(+)-ETHYLMETHYLCARBINOL
  • D-(+)-SEC-BUTYL ALCOHOL
  • D-SEC-BUTYL ALCOHOL
  • (S)-(+)-sec-Butanol,99%
  • (S)-(+)-2-Butanol,(S)-(+)-sec-Butyl alcohol
CAS:
4221-99-2
MF:
C4H10O
MW:
74.12
EINECS:
224-168-1
Product Categories:
  • chiral
  • Chiral Compounds (Building Blocks for Liquid Crystals)
  • Building Blocks for Liquid Crystals
  • Chiral Building Blocks
  • Functional Materials
  • Simple Alcohols (Chiral)
  • Alcohols, Hydroxy Esters and Derivatives
  • Chiral Compounds
  • Synthetic Organic Chemistry
Mol File:
4221-99-2.mol
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(S)-(+)-2-Butanol Chemical Properties

Melting point:
-114 °C
Boiling point:
99-100 °C (lit.)
alpha 
13 º (neat)
Density 
0.803 g/mL at 25 °C (lit.)
vapor density 
2.6 (vs air)
vapor pressure 
12.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.397(lit.)
Flash point:
80 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
pka
15.31±0.20(Predicted)
color 
Clear colorless
Odor
at 1.00 % in dipropylene glycol. oily wine
Odor Type
oily
optical activity
[α]20/D +13°, neat
explosive limit
9.8%
Water Solubility 
125 g/L (20 ºC)
Merck 
14,1541
BRN 
1718763
Stability:
Stable. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents, halogens.
LogP
0.691 (est)
CAS DataBase Reference
4221-99-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Butanol, (S)-(+)-(4221-99-2)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37-67
Safety Statements 
9-13-24-25-26-46-7/9-24/25
RIDADR 
UN 1120 3/PG 3
OEB
A
OEL
TWA: 100.0 ppm; 305.0 mg/m3, STEL: 150.0 ppm; 455.0 mg/m3
WGK Germany 
1
RTECS 
EO1750000
Autoignition Temperature
761 °F
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
III
HS Code 
29051490

MSDS

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(S)-(+)-2-Butanol Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

(S)-(+)-2-Butanol can be used:

  • To synthesize chiral asymmetric perylene diimides (PDI) that spontaneously self-assemble into one-handed nanotubes that are photoconductive or fluorescent in nature.
  • To synthesize bulky chiral vinyl monomers that can be radically polymerized to helical polymers with an excess screw sense.
  • As chiral solvent to study excited state photo transfer of the photoacid, 5,8-dicyano-2-naphthol (DCN2) in chiral environment.

Definition

ChEBI: (2S)-butan-2-ol is a butan-2-ol. It is an enantiomer of a (2R)-butan-2-ol.

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