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CRUFOMATE

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CRUFOMATE Basic information

Product Name:
CRUFOMATE
Synonyms:
  • RUELENE (TM)
  • MONTREL
  • crufomate (bsi,iso,ansi)
  • 4-TERT-BUTYL-2-CHLOROPHENYLMETHYLMETHYLPHOSPHORAMIDE
  • (4-tetra-Butyl-2-chlorophenylmethyl methylphosphoramidate
  • crufomat (ISO) 4-tert-butyl-2-chlorophenyl methyl methylphosphoramidate
  • DOWCO 132
  • ENT 25602-X
CAS:
299-86-5
MF:
C12H19ClNO3P
MW:
291.71
EINECS:
206-083-1
Mol File:
299-86-5.mol
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CRUFOMATE Chemical Properties

Melting point:
60℃
Boiling point:
bp0.01 117-118°
Density 
1.176
refractive index 
nD20 1.5142
form 
solid
pka
0.05±0.70(Predicted)
Water Solubility 
4.975g/L(temperature not stated)
EPA Substance Registry System
Crufomate (299-86-5)
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
21/22-50/53
Safety Statements 
36/37-60-61
RIDADR 
UN2783 (solid)
OEB
B
OEL
TWA: 5 mg/m3, STEL: 20 mg/m3
HS Code 
29299090
Hazardous Substances Data
299-86-5(Hazardous Substances Data)
Toxicity
LD50 in male, female rats (mg/kg): 635, 460 orally (Gaines)
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CRUFOMATE Usage And Synthesis

Description

Crufomate is a white crystalline solid; thecommercial product is a yellow oil. Molecularweight=291.71; Boiling point=(decomposes); Freezing/Melting point=(decomposes) 63℃. Insoluble in water.

Chemical Properties

Crufomate is a white crystalline solid; the commercial product is a yellow oil.

Uses

Systemic insecticide and anthelmintic.

Uses

Crufomate is an organophosphate pesticide. Crufomate is an anthelmintic that functions as a potent inhibitor of an acetylcholinesterase in the anterior end of the worms. Crufomate is also used to combat bovine hypodermatosis.

Definition

ChEBI: Crufomate is an alkylbenzene.

General Description

White crystalline solid Mp: 61.5°C. The commercial product is a yellow oil. A phosphoramidate insecticide.

Reactivity Profile

CRUFOMATE is combustible; liquid formulations containing organic solvents may be flammable. Incompatible with strongly basic and strongly acidic materials. Unstable over long periods in aqueous preparations or above140°F. Emits toxic fumes of POx, Cl2 and NOx when heated to decomposition (Hazardous Chemicals Desk Reference p. 272 (1987)).

Hazard

Cholinesterase inhibitor. Questionable carcinogen.

Agricultural Uses

Insecticide, Anthelmintic (for cattle): All residue limits for crufomate, as listed in 40 CFR 180.295, were revoked by the U.S. EPA on June 9, 1993. All registered uses of crufomate in or on fat, meat, and meat byproducts of cattle, goats, and sheep were canceled It is applied as a spray on plants to kill insects, grubs, and worms on cattle. Not listed for use in EU countries

Trade name

DOWCO® 132[C]; MONTREL®[C]; RUELENE®[C]; DRENCH®[C]; RULENE®[C]

Potential Exposure

A potential danger to those involved in the manufacture, formulation, and application of this insecticide and anthelmintic for cattle.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Speed in removing material from skinis of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, beginrescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24-36 h.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool wellventilated area away from heat. Also, avoid contact withoxidizers (such as peroxides, permanganates, chlorates, perchlorates, and nitrates).

Shipping

UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Contact with oxidizers may cause the release of phosphorous oxides. Contact with strong reducing agents, such as hydrides, may cause the formation of flammable and toxic phosphine gas. Decomposes on heating, forming corrosive and toxic fumes of hydrogen chloride and nitrogen and phosphorous oxides. Incompatible with strongly alkaline and strongly acidic media. Unstable over long periods in aqueous preparations or above 60°C.

Waste Disposal

Crufomate decomposes above pH 7.0 in alkaline media. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

CRUFOMATESupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Email
cdhxsj@163.com
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Email
800078821@qq.com
The future of Shanghai Industrial Co., Ltd.
Tel
021-61552785
Email
sales@shshiji.com
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