Basic information Safety Supplier Related

Palladacycle Gen. 3

Basic information Safety Supplier Related

Palladacycle Gen. 3 Basic information

Product Name:
Palladacycle Gen. 3
Synonyms:
  • CPHOS PALLADACYCLE GEN. 3
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%
  • METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',6'-BIS(DIMETHYLAMINO)-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[CPHOSPALLADACYCLEGEN.3]
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3
  • Palladacycle Gen. 3
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3
  • Palladacycle Gen. 3 ISO 9001：2015 REACH
  • CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CAS:
1447963-73-6
MF:
C41H54N3O3PPdS
MW:
806.35
Product Categories:
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
Mol File:
1447963-73-6.mol
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Palladacycle Gen. 3 Chemical Properties

Melting point:
176-178 °C (decomposition)
form 
Powder
color 
white to off-white
InChI
InChI=1S/C28H41N2P.C12H9N.CH4O3S.Pd/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-23H,5-10,14-17H2,1-4H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
InChIKey
BYZMMBLECCTRMT-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1N(C)C)N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
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Palladacycle Gen. 3 Usage And Synthesis

Reactions

  1. Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides
  2. Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles

General Description

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Palladacycle Gen. 3Supplier

xinxiang runyu material co.,Ltd Gold
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