Bis(benzonitrile)palladium chloride Chemical Properties

Melting point:

131 °C(lit.)

storage temp. 

Inert atmosphere,2-8°C

solubility 

Soluble in acetone, chloroform

form 

Crystalline Powder

color 

Orange to brown

Water Solubility 

insoluble

Hydrolytic Sensitivity

4: no reaction with water under neutral conditions

BRN 

3981730

Exposure limits

NIOSH: IDLH 25 mg/m3

InChI

InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChIKey

WXNOJTUTEXAZLD-UHFFFAOYSA-L

SMILES

C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl

CAS DataBase Reference

14220-64-5(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21-23/24/25

Safety Statements 

22-24/25-23-45-36/37-27-20-9-4

RIDADR 

UN3439

WGK Germany 

3

F 

9

TSCA 

No

HazardClass 

6.1

PackingGroup 

III

HS Code 

28439090

MSDS

• Language:English Provider:Bis(benzonitrile)palladium chloride
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• Language:English Provider:SigmaAldrich
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Bis(benzonitrile)palladium chloride Usage And Synthesis

Reaction

1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
2. Catalyst for the aza-Michael reaction of carbamates with enones.
3. Catalyst for the rearrangement of allylic imidates to allylic amides.
4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
5. Catalyst for the diamination of conjugated dienes.
6. Three component Michael addition, cyclization, cross-coupling reaction.
7. C-H activation of indoles.

Bis(benzonitrile)palladium chloride(14220-64-5)Related Product Information

• Benzonitrile
• Calcium chloride
• Choline chloride
• FENBUCONAZOLE
• 4-Aminobenzonitrile
• Phthalonitrile
• 4-Nitrobenzonitrile
• Palladium chloride
• Potassium chloride
• Sodium chloride
• Methyl 4-cyanobenzoate
• Palladium
• 2-Cyanophenol
• 4-Cyanophenol
• Ammonium chloride
• Bis(dibenzylideneacetone)palladium
• [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
• Tetrakis(triphenylphosphine)platinum