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Bis(benzonitrile)palladium chloride

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Bis(benzonitrile)palladium chloride Basic information

Product Name:
Bis(benzonitrile)palladium chloride
Synonyms:
  • TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE
  • Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2
  • Pd(PhCN)2Cl2
  • trans-Bis(benzonitrile)palladiuM chloride
  • Dichlorobis(benzonitrile)palladium(Ⅱ)
  • Benzonitrile, palladium complex
  • Bis(phenylnitrile)dichloropalladium
  • Dibenzonitrilepalladium dichloride
CAS:
14220-64-5
MF:
C14H10Cl2N2Pd
MW:
383.57
EINECS:
238-085-3
Product Categories:
  • organometallic complexes
  • Metal Compounds
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • chemical reaction,pharm,electronic,materials
  • Pd
Mol File:
14220-64-5.mol
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Bis(benzonitrile)palladium chloride Chemical Properties

Melting point:
131 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in acetone, chloroform
form 
Crystalline Powder
color 
Orange to brown
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3981730
Exposure limits
NIOSH: IDLH 25 mg/m3
InChI
InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey
WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES
C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference
14220-64-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21-23/24/25
Safety Statements 
22-24/25-23-45-36/37-27-20-9-4
RIDADR 
UN3439
WGK Germany 
3
9
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
28439090

MSDS

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Bis(benzonitrile)palladium chloride Usage And Synthesis

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Reactions of 14220-64-5_2
Reactions of 14220-64-5_1

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Preparation Products

Raw materials

Bis(benzonitrile)palladium chlorideSupplier

Shaanxi Rock New Materials Co., Ltd. Gold
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0917-8888777, 3380777,18691786767; 15619786767
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Nanjing Pharmaluxury Co., Ltd. Gold
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