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(S)-(-)-METHYL P-TOLYL SULFOXIDE

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(S)-(-)-METHYL P-TOLYL SULFOXIDE Basic information

Product Name:
(S)-(-)-METHYL P-TOLYL SULFOXIDE
Synonyms:
  • (S)-(-)-METHYL P-TOLYL SULFOXIDE, 99% (9
  • (S)-(-)-METHYL P-TOLYL SULFOXIDE
  • 1-Methyl-4-[(S)-methylsulfinyl]benzene
  • S-(4-Methylphenyl) methyl sulfoxide
  • (S)-Methyl 4-tolyl sulfoxide
  • (S)-Methyl p-methylphenyl sulfoxide
  • (S)-p-Methylphenyl methyl sulfoxide
  • (S)-p-Tolyl methyl sulfoxide
CAS:
5056-07-5
MF:
C8H10OS
MW:
154.23
Product Categories:
  • Chiral Compound
  • Chiral Building Blocks
  • Organic Building Blocks
  • Sulfoxides
Mol File:
5056-07-5.mol
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(S)-(-)-METHYL P-TOLYL SULFOXIDE Chemical Properties

Melting point:
75-77 °C(lit.)
Boiling point:
282.4±19.0 °C(Predicted)
Density 
1.15±0.1 g/cm3(Predicted)
optical activity
[α]20/D 145°, c = 2 in acetone
BRN 
2324696
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Safety Information

WGK Germany 
3
3-10

MSDS

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(S)-(-)-METHYL P-TOLYL SULFOXIDE Usage And Synthesis

Uses

(S)-(-)-Methyl p-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize:

  • Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
  • α-substituted N-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methyl p-tolyl sulfoxide anion.
  • 2-O-benzyl-3,4-O-isopropylidene-L-erythrose by one-carbon homologation of 2,3-O-isopropylidene-L-glyceraldehyde.

(S)-(-)-METHYL P-TOLYL SULFOXIDESupplier

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