TIN(II) TRIFLUOROMETHANESULFONATE Chemical Properties

Melting point:

≥300 °C (lit.)

storage temp. 

Inert atmosphere,2-8°C

form 

Powder

color 

White to yellow

Water Solubility 

Insoluble in water.

Sensitive 

Moisture Sensitive

Stability:

hygroscopic

CAS DataBase Reference

62086-04-8(CAS DataBase Reference)

Safety Information

Hazard Codes 

C,Xi

Risk Statements 

34-36/37/38

Safety Statements 

26-36/37/39-45-37/39

RIDADR 

UN 3146 6.1/PG 3

WGK Germany 

3

F 

1-10

Hazard Note 

Corrosive

TSCA 

No

HazardClass 

6.1

PackingGroup 

III

HS Code 

29049090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

TIN(II) TRIFLUOROMETHANESULFONATE Usage And Synthesis

Description

Mild Lewis acid, primarily used to generate tin(II) enolates for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements; addition of tin(II) acetylides to aldehydes; asymmetric allylation of aldehydes.

Chemical Properties

White to yellowish powder

Uses

Tin(II) trifluoromethanesulfonate is a mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements, Horner-Wadsworth-Emmons reactions, asymmetric [3 + 2] cycloaddition, ring opening reactions and Friedel-Crafts reactions.

reaction suitability

core: tin
reagent type: catalyst

storage

Moisture and air sensitive; all handling and storage should be done under nitrogen.

TIN(II) TRIFLUOROMETHANESULFONATE(62086-04-8)Related Product Information

• SAMARIUM(III) TRIFLUOROMETHANESULFONATE
• YTTRIUM(III) TRIFLUOROMETHANESULFONATE
• YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
• Sodium trifluoromethanesulfonate
• Trifluoromethanesulfonamide
• Ethyl trifluoromethanesulfonate
• Trimethylsilyl trifluoromethanesulfonate
• INDIUM(III) TRIFLUOROMETHANESULFONATE
• EUROPIUM TRIFLUOROMETHANESULFONATE
• Iron(III) trifluoromethanesulfonate
• (Trifluoromethylsulfonyloxy) copper(I)
• Lithium trifluoromethanesulfonate
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• Sodium trifluoromethanesulfinate
• MAGNESIUM TRIFLUOROMETHANESULFONATE
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