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4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL

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4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Basic information

Product Name:
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
Synonyms:
  • 4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl 
  • 4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy,freeradical
  • 4-methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxy
  • 4-METHOXY-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY, FREE RADICAL
  • 4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
  • 4-METHOXY-TEMPO
  • 4-METHOXY-TEMPO, FREE RADICAL
  • (2,2,6,6-Tetramethyl-4-methoxypiperidinooxy)radical
CAS:
95407-69-5
MF:
C10H20NO2*
MW:
186.27
EINECS:
619-125-2
Product Categories:
  • Analytical Chemistry
  • ESR Spectrometry
  • Oxidation
  • Spin Labels
  • Synthetic Organic Chemistry
Mol File:
95407-69-5.mol
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4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Chemical Properties

Melting point:
40.5-44 °C (lit.)
storage temp. 
2-8°C
form 
powder to crystal
color 
Orange to Amber to Dark red
BRN 
4740399
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2933399990

MSDS

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4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Usage And Synthesis

Uses

4-Methoxy-TEMPO may be employed as catalyst for the synthesis of 2-substituted benzoxazoles, via aerobic oxidation reaction.

General Description

4-Methoxy-TEMPO (4-methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy) is an aminoxyl free radical commonly employed for the oxidation reaction of alcohols (primary/secondary). It has been proposed as hindered amine light stabiliser (HALS) model compound. Its reaction with irradiated dilute aqueous suspensions of photocatalytic nanoparticulate titanium dioxide was investigated by electron spin resonance (ESR) and electrospray ionization mass-spectrometry (ESI-MS).

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