Basic information Safety Supplier Related

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE

Basic information Safety Supplier Related

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Basic information

Product Name:
DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE
Synonyms:
  • DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE
  • Diisopropyl (carboethoxymethyl)phosphonate
  • Ethyl (diisopropyl phosphono)acetate
  • Acetic acid, 2-[bis(1-methylethoxy)phosphinyl]-, ethyl ester
  • ethyl 2-di(propan-2-yloxy)phosphorylacetate
  • Ethyl 2-(diisopropoxyphosphoryl)acetate
CAS:
24074-26-8
MF:
C10H21O5P
MW:
252.24
Product Categories:
  • C-C Bond Formation
  • Horner-Wadsworth-Emmons Reagents
  • Olefination
Mol File:
24074-26-8.mol
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DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Chemical Properties

Boiling point:
142-143 °C11 mm Hg(lit.)
Density 
1.06 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.427(lit.)
Flash point:
>230 °F
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3

MSDS

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DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATE Usage And Synthesis

Uses

Reactant for:

  • Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization
  • Katsuki-Sharpless epoxidation reaction
  • Preparation of nine-membered diallylic sulfonamides as chiral building blocks
  • Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds
  • Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells
  • Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)

DIISOPROPYL (ETHOXYCARBONYLMETHYL)PHOSPHONATESupplier

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