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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL

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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Basic information

Product Name:
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
Synonyms:
  • (S)-(+)-2,2,2-TRIFLUORO-1-PHENYLETHANOL
  • (S)-2,2,2-TRIFLUORO-1-PHENYL-ETHANOL
  • (S)-(+)-1-PHENYL-2,2,2-TRIFLUOROETHANOL
  • (S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
  • (+)-PHENYL(TRIFLUOROMETHYL)CARBINOL
  • (S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL AL COHOL, 99% (97% EE/GLC)
  • (s)-(+)-α-(trifluoromethyl)benzyl alcohol
  • (+)-Phenyl(trifluoromethyl)carbinol, (S)-(+)-1-Phenyl-2,2,2-trifluoroethanol
CAS:
340-06-7
MF:
C8H7F3O
MW:
176.14
EINECS:
206-430-7
Product Categories:
  • Alcohols, Hydroxy Esters and Derivatives
  • Chiral Compounds
Mol File:
340-06-7.mol
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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Chemical Properties

Boiling point:
73-76 °C9 mm Hg(lit.)
Density 
1.3 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.462(lit.)
Flash point:
184 °F
storage temp. 
Inert atmosphere,Room Temperature
form 
Liquid
pka
11.91±0.10(Predicted)
color 
Clear colorless to pale yellow
optical activity
[α]20/D +31.3±0.5°, neat
BRN 
2327547
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Safety Information

Hazard Codes 
Xi,C
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
10-23
HS Code 
29062990

MSDS

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(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Usage And Synthesis

Uses

(S)?-?(+)?-?α-?(Trifluoromethyl)?benzyl Alcohol is used in the synthesis of metal-organic framework compounds which may have mesoporous properties.

Purification Methods

Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.]

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