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D-(-)-Asparagine monohydrate

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D-(-)-Asparagine monohydrate Basic information

Product Name:
D-(-)-Asparagine monohydrate
Synonyms:
  • ASPARAGINE, D-
  • ASPARAGINE
  • (D)-ASPARTIC ACID 4-AMIDE
  • D-ASPARAGINE
  • (R)-2-AMINOSUCCINIC ACID 4-AMIDE
  • (R)-2-Aminosuccinamic acid
  • H-D-Asn-OH·H2O
  • D-2-Aminosuccinamic acid
CAS:
2058-58-4
MF:
C4H8N2O3
MW:
132.12
EINECS:
218-163-3
Product Categories:
  • Amino Acids and Derivatives
  • Amino Acids
  • Amino Acids Derivatives
Mol File:
2058-58-4.mol
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D-(-)-Asparagine monohydrate Chemical Properties

Melting point:
280 °C (dec.) (lit.)
alpha 
-35 º (c=5, 5M HCl)
Boiling point:
438.0±40.0 °C(Predicted)
Density 
1.404±0.06 g/cm3(Predicted)
storage temp. 
Store at 0-5°C
solubility 
Aqueous Acid (Sparingly), Water (Slightly, Sonicated)
form 
Solid
pka
2.17(at 20℃)
color 
White to Off-White
optical activity
[α]20/D 35°, c = 5 in 5 M HCl
Merck 
13,842
BRN 
1723526
Stability:
Hygroscopic
InChIKey
DCXYFEDJOCDNAF-UWTATZPHSA-N
LogP
-1.880 (est)
CAS DataBase Reference
2058-58-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
1
HS Code 
29241900

MSDS

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D-(-)-Asparagine monohydrate Usage And Synthesis

Chemical Properties

crystalline powder

Uses

D-Asparagine is an isomer of L-Asparagine (A790005) and is used by bacteria (such as Saccharomyces cerevisiae) as a sole nitrogen source for replication. L-Asparagine is also a competitive inhibitor of staphylococcal L-asparaginase and is used as a reagent to synthesize peptide antibiotics.

Definition

ChEBI: An optically active form of asparagine having D-configuration.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 35, p. 2994, 1987 DOI: 10.1248/cpb.35.2994

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