Bis(4-methylphenyl)iodonium hexafluorophosphate Chemical Properties

form 

solid

BRN 

3581445

InChI

InChI=1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1

InChIKey

LHLVGWWCRPPKBC-UHFFFAOYSA-N

SMILES

[P-](F)(F)(F)(F)(F)F.[I+](C1C=CC(=CC=1)C)C1=CC=C(C=C1)C

CAS DataBase Reference

60565-88-0(CAS DataBase Reference)

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-36/37/39-45

RIDADR 

UN 1759 8 / PGII

WGK Germany 

3

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Skin Corr. 1B

Bis(4-methylphenyl)iodonium hexafluorophosphate Usage And Synthesis

Uses

• Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).


• Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).


• Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

General Description

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Bis(4-methylphenyl)iodonium hexafluorophosphate(60565-88-0)Related Product Information

• Potassium hexafluorophosphate
• Lithium hexafluorophosphate
• Xylene
• Sodium hexafluorophosphate
• Hexafluorophosphoric acid
• DIPHENYLIODONIUM IODIDE
• Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
• Diphenyliodonium hexafluorophosphate
• Bis(4-methylphenyl)iodonium hexafluorophosphate