ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Basic information
- Product Name:
- ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
- Synonyms:
-
- (1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate
- (1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I)
- Acetylacetonato(1,5-cyclooctadiene)rhodium(I),97%
- Acetylacetonato(1,5-
- (Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ)
- NSC 240030
- RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE
- ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodiu
- CAS:
- 12245-39-5
- MF:
- C13H19O2Rh
- MW:
- 310.19
- Product Categories:
-
- organometallic complex
- Rh
- Mol File:
- 12245-39-5.mol
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties
- Melting point:
- 138-140 °C(lit.)
- storage temp.
- Inert atmosphere,2-8°C
- form
- Crystals
- color
- Yellow to orange
- Sensitive
- Air Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - InChIKey
- WDIAJTWVVLHUJU-SUESZSCISA-N
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MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Usage And Synthesis
Reactions
- Precursor for asymmetric hydrogenation reactions.
- Rh-catalyzed carbozincation of ynamides.
Chemical Properties
Orange crystal
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
General Description
Atomic number of base material: 45 Rhodium
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)Supplier
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