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Carbonyldihydrotris(triphenylphosphine)ruthenium

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Carbonyldihydrotris(triphenylphosphine)ruthenium Basic information

Product Name:
Carbonyldihydrotris(triphenylphosphine)ruthenium
Synonyms:
  • RUTHENIUM DIHYDRIDO CARBONYL TRIS (TRIPHENYLPHOSPHINE)
  • CARBONYLDIHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
  • CARBONYL(DIHYDRIDO)TRIS(TRIPHENYLPHOSPINERUTHENIUM(II))
  • CARBONYLDIHYDRIDO TRIS(TRIPHONYLPHOSPHANE)RUTHENIUM(II)
  • Dihydridocarbonyltris(triphenylphosphine) ruthenium
  • Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II),99%
  • Carbonyl(dihydrido)tris(triphenyl phosphine)ruthenium
  • Dihydridocarbonyltris-(triphenylphosphino)-ruthenium
CAS:
25360-32-1
MF:
C55H45OP3Ru
MW:
915.94
Product Categories:
  • chemical reaction,pharm,electronic,materials
  • Ru
  • Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Ru Catalysts
  • metal carbonyl complexes
  • Classes of Metal Compounds
  • Ru (Ruthenium) Compounds
  • Transition Metal Compounds
  • Ruthenium
Mol File:
25360-32-1.mol
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Carbonyldihydrotris(triphenylphosphine)ruthenium Chemical Properties

Melting point:
161-163 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
form 
Powder
color 
white to off-white
Water Solubility 
Insoluble in water.
Sensitive 
Moisture Sensitive
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36
RIDADR 
UN2813
WGK Germany 
3
HazardClass 
4.3
PackingGroup 
III
HS Code 
28439000

MSDS

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Carbonyldihydrotris(triphenylphosphine)ruthenium Usage And Synthesis

Reaction

  1. Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.
  2. Catalytic C-C bond formation.
  3. Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.
  4. Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.
  5. Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.
  6. Precatalyst for hydrogen production by means of alcohol dehydrogenation. 

Chemical Properties

White to off-white powder

Uses

&bull Catalyst for conversion of 1,4-alkynediols into pyrroles &bull Catalyst for oxidation of primary alcohols to methyl esters &bull Catalyst for rearrangement of oximes to amides &bull Catalyst for C-C coupling via directed C-H activation &bull Cata

Uses

Carbonyldihydrotris(triphenylphosphine)ruthenium(II) is a catalyst used in the preparation of ruthenium (diphenylphosphino)ethyl)amine complexes pre-catalysts for hydrogenation and dehydrogenation.

Uses

  • Catalyst for conversion of 1,4-alkynediols into pyrroles
  • Catalyst for oxidation of primary alcohols to methyl esters
  • Catalyst for rearrangement of oximes to amides
  • Catalyst for C-C coupling via directed C-H activation
  • Catalyst for enyne cyclization

Carbonyldihydrotris(triphenylphosphine)rutheniumSupplier

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