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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic palladium >  ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98

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ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Basic information

Product Name:
ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
Synonyms:
  • [1,3-bis(2,6-diisopropylphenyl)-2H-imidazol-2-yl]-chloro-palladium
  • Allylchloro[1,3-bis(2,6-di-i-propylphenyl)
  • imidazol-2-ylidene]palladium(II)
  • ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
  • PALLADIUM(II)
  • ALLYLCHLORO[1,3-BIS-(DIISOPROPYLPHENYL)-IMIDAZOLE-2-YLIDENE]PALLADIUM(II)
  • Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium
  • Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) 98%
CAS:
478980-03-9
MF:
C30H41ClN2Pd
MW:
571.53
Product Categories:
  • Pd
  • alkylidene complex
Mol File:
478980-03-9.mol
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ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Chemical Properties

Melting point:
190°C (dec.)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
white
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
HS Code 
28439000
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ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Usage And Synthesis

Reaction

  1. Catalyst for the cross-coupling of aryl chlorides with boronic acids.
  2. Catalyst for the diamination of conjugated dienes and trienes.
  3. Catalyst for the dehalogenation of aryl chlorides.
  4. Catalyst for anaerobic alcohol oxidation.
  5. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. 

Chemical Properties

Yellow crystal

Uses

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.

General Description

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98Supplier

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