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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Basic information

Product Name:
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonyms:
  • DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
  • DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
  • [Bis(diphenylphosphino)ethane]dichloronickel
  • 1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE
  • [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II)
  • 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE
  • [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE
  • 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%
CAS:
14647-23-5
MF:
C26H24Cl2NiP2
MW:
528.02
EINECS:
629-489-4
Product Categories:
  • API intermediates
  • Catalysis and Inorganic Chemistry
  • Metal Compounds
  • Catalysts for Organic Synthesis
  • Chemical Synthesis
  • Ni
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Ni (Nickel) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • metal-phosphine complexes
Mol File:
14647-23-5.mol
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties

Melting point:
263-265 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform, Methanol (Sparingly)
form 
crystal
color 
orange
Water Solubility 
insoluble
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:
Hygroscopic
CAS DataBase Reference
14647-23-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T,Xn
Risk Statements 
45-20/21/22-36/37/38-42/43-40
Safety Statements 
53-22-26-36-45-52
WGK Germany 
3
TSCA 
No
HS Code 
29319090

MSDS

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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Usage And Synthesis

Chemical Properties

Orange to red crystalline powder

Uses

suzuki reaction

Uses

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

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