ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Basic information
- Product Name:
- 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
- Synonyms:
-
- DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
- DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
- [Bis(diphenylphosphino)ethane]dichloronickel
- 1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE
- [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II)
- 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE
- [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE
- 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%
- CAS:
- 14647-23-5
- MF:
- C26H24Cl2NiP2
- MW:
- 528.02
- EINECS:
- 629-489-4
- Product Categories:
-
- API intermediates
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Ni
- Metal Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Ni (Nickel) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- metal-phosphine complexes
- Mol File:
- 14647-23-5.mol
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties
- Melting point:
- 263-265 °C(lit.)
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Chloroform, Methanol (Sparingly)
- form
- crystal
- color
- orange
- Water Solubility
- insoluble
- Exposure limits
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
- Stability:
- Hygroscopic
- InChI
- InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
- InChIKey
- XXECWTBMGGXMKP-UHFFFAOYSA-L
- SMILES
- [Ni+2].C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Cl-].[Cl-]
- CAS DataBase Reference
- 14647-23-5(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- T,Xn
- Risk Statements
- 45-20/21/22-36/37/38-42/43-40
- Safety Statements
- 53-22-26-36-45-52
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Usage And Synthesis
Chemical Properties
Orange to red crystalline powder
Uses
suzuki reaction
Uses
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
reaction suitability
core: nickel
reagent type: catalyst
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Preparation Products And Raw materials
Raw materials
1,2-Bis(diphenylphosphino)ethane nickel(II) chlorideSupplier
Puyang Huicheng Electronic Material Co. Ltd. Gold
- Tel
- 0393-0393-0393-8910800 15039333257
- info@huichengchem.com
Panjin Greenchem Technology Co., Ltd. Gold
- Tel
- 13121959385
- chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006356688 18621169109
- market03@meryer.com
Beijing Donghualituo Techonlogy Development Co.,Ltd.
- Tel
- 010-88425576
- sales@dhltchem.com
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5)Related Product Information
- Calcium chloride
- Polyvinyl chloride
- Ammonium chloride
- Choline chloride
- ETHANE
- Sodium chloride
- Diphenylphosphine oxide
- Hexafluoroethane
- Diphenylphosphine
- Chlorodiphenylphosphine
- 1,1'-Bis(diphenylphosphino)ferrocene
- (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- Nickel(II) chloride hexahydrate
- Nickle chloride
- Potassium chloride
- Methylene Chloride
- 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE
- 1,2-Bis(diphenylphosphino)ethane