CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Basic information
- Product Name:
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
- Synonyms:
-
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
- CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE
- BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE
- BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE
- IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE
- CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- VASKA'S COMPLEX
- carbonylchlorobis(triphenylphosphine)-iridiu
- CAS:
- 14871-41-1
- MF:
- C37H30ClIrOP2
- MW:
- 780.25
- EINECS:
- 238-941-6
- Product Categories:
-
- Ir
- Mol File:
- 14871-41-1.mol
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties
- Melting point:
- 215°C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol
- form
- crystal
- color
- lemon yellow
- λmax
- 385nm(lit.)
- InChIKey
- KMVALWICXMGTQO-UHFFFAOYSA-M
- CAS DataBase Reference
- 14871-41-1(CAS DataBase Reference)
- EPA Substance Registry System
- Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Usage And Synthesis
Reaction
- Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
- Catalyst for the selective hydrogenation of myrcene.
- Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
- Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
- Hydrogen atom transfer catalyst for radical cyclizations.
- Complex for photocatalytic alkane dehydrogenation.
- Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
- Catalyst for chemoselective reductive alkynylation of tertiary amides.
Chemical Properties
GREEN FINE CRYSTALLINE POWDER
Uses
Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.
Application
Carbonylchlorobis(triphenylphosphine)iridium(I) can be used as a catalyst precursor for homogeneous hydrogenation, decarbonylation of acyl halides, hydrosilylation of olefins, and hydroboration.
Preparation
In a round-bottomed flask a mixture containing 3.52 g (10 mmol) of IrCl3.3H2O, 13.1 g (50 mmol) of PPh3, 4 mL of aniline, and 150 mL of DMF is heated under nitrogen at reflux for 12 h. After filtering the resulting redbrown solution hot, 300 mL of warm methanol is added rapidly and the mixture stirred. Upon cooling in an ice bath, yellow crystals of Carbonylchlorobis(triphenylphosphine)iridium(I) are collected on a filter and washed with 250 mL of methanol and then with 25 mL of diethyl ether (87-90%).
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CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)(14871-41-1)Related Product Information
- HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- Bis(triphenylphosphine)palladium(II) chloride
- Chloro(1,5-cyclooctadiene)rhodium(I) dimer
- Carbonylchlorohydrotris(triphenylphosphine)ruthenium
- Carbonyldihydrotris(triphenylphosphine)ruthenium
- Iridium(III) chloride hydrate
- Iridium
- Diphenylphosphine
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
- CARBON MONOXIDE
- (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
- Rhodium (triphenylphosphine)carbonylacetylacetonate