CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties

Melting point:

215°C

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol

form 

crystal

color 

lemon yellow

λmax

385nm(lit.)

InChIKey

KMVALWICXMGTQO-UHFFFAOYSA-M

CAS DataBase Reference

14871-41-1(CAS DataBase Reference)

EPA Substance Registry System

Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)

Safety Information

Risk Statements 

20/21/22

Safety Statements 

22-24/25

RIDADR 

UN2811

WGK Germany 

3

TSCA 

Yes

HS Code 

2931.90.6000

HazardClass 

6.1

PackingGroup 

III

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Usage And Synthesis

Reaction

1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
2. Catalyst for the selective hydrogenation of myrcene.
3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
5. Hydrogen atom transfer catalyst for radical cyclizations.
6. Complex for photocatalytic alkane dehydrogenation.
7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
8. Catalyst for chemoselective reductive alkynylation of tertiary amides.

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)(14871-41-1)Related Product Information

• HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
• Bis(triphenylphosphine)palladium(II) chloride
• Chloro(1,5-cyclooctadiene)rhodium(I) dimer
• Carbonylchlorohydrotris(triphenylphosphine)ruthenium
• Carbonyldihydrotris(triphenylphosphine)ruthenium
• Iridium(III) chloride hydrate
• Iridium
• Diphenylphosphine
• CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
• CARBON MONOXIDE
• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE