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(1R,2R)-(+)-1,2-Diphenylethylenediamine

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(1R,2R)-(+)-1,2-Diphenylethylenediamine Basic information

Product Name:
(1R,2R)-(+)-1,2-Diphenylethylenediamine
Synonyms:
  • (R,R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE
  • (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ee
  • (1S,2S)-1,2-Diphenyl-1,2-diaminoethane
  • (αS,βS)-Bibenzyl-α,β-diamine
  • (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine ,98% [99%,e.e.]
  • (1R,2R)-(+)-1,2-Diphenylethylenediamine ,99% [ee:99%]
  • (1R,2R)-Diphenyl-1,2-ethanediamine
  • (1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine, 98+%, ee 98%
CAS:
35132-20-8
MF:
C14H16N2
MW:
212.29
EINECS:
609-071-8
Product Categories:
  • Chiral Nitrogen
  • DPEN Series
  • chiral
  • Chiral reagent
  • CHIRAL COMPOUNDS
  • organic amine
  • Amines (Chiral)
  • Analytical Chemistry
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • e.e. / Absolute Configuration Determination (NMR)
  • Aromatics
  • Chiral Reagents
  • Miscellaneous Reagents
  • Enantiomer Excess & Absolute Configuration Determination
  • Synthetic Organic Chemistry
  • Amines and Derivatives
  • CHIRAL CHEMICALS
  • Chiral Compound
Mol File:
35132-20-8.mol
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(1R,2R)-(+)-1,2-Diphenylethylenediamine Chemical Properties

Melting point:
79-83 °C(lit.)
alpha 
104 º (c=1.1, MeOH 25 ºC)
Boiling point:
342.14°C (rough estimate)
Density 
1.0799 (rough estimate)
refractive index 
103 ° (C=1, EtOH)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Crystalline Powder
pka
9.78±0.10(Predicted)
color 
White to light yellow
optical activity
[α]20/D +102°, c = 1 in ethanol
Water Solubility 
Insoluble in water.
Sensitive 
Air Sensitive
BRN 
2369988
Stability:
Hygroscopic
InChIKey
PONXTPCRRASWKW-ZIAGYGMSSA-N
CAS DataBase Reference
35132-20-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,C
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-23
HazardClass 
8
HS Code 
29212900

MSDS

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(1R,2R)-(+)-1,2-Diphenylethylenediamine Usage And Synthesis

Description

(1R,2R)-(+)-1,2-Diphenylethylenediamine is a chiral reagent widely used in the chemical industry at present, used for asymmetric synthesis and optical resolution.

Chemical Properties

white to light yellow crystal powder

Uses

(1R,2R)-(+)-1,2-Diphenyl-1,2-ethanediamine is used as chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR. It is used in various catalyst systems for asymmetric reactions.

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