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1-[(2,5-dimethoxyphenyl)azo]-2-naphthol

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1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Basic information

Product Name:
1-[(2,5-dimethoxyphenyl)azo]-2-naphthol
Synonyms:
  • Blueberry red pigment
  • C.I.12156
  • C.I.Solvent Red 80
  • 1-((2,5-DiMethoxyphenyl)diazenyl)naphthalen-2-ol
  • 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol
  • Solvent Red 80.
  • 1-(2,5-DIMETHYLPHENYLAZO)-2-NAPHTHOL
  • CITRUSRED
CAS:
6358-53-8
MF:
C18H16N2O3
MW:
308.33
EINECS:
228-778-9
Product Categories:
  • dyestuff
Mol File:
6358-53-8.mol
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1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Chemical Properties

Melting point:
155-157°
Boiling point:
448.73°C (rough estimate)
Density 
1.2510 (rough estimate)
refractive index 
1.5700 (estimate)
pka
13.61±0.50(Predicted)
Colour Index 
12156
BRN 
4510811
LogP
3.129 (est)
IARC
2B (Vol. 8, Sup 7) 1987
EPA Substance Registry System
Citrus Red No. 2 (6358-53-8)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
40
Safety Statements 
45
WGK Germany 
3
RTECS 
QL3675000
Hazardous Substances Data
6358-53-8(Hazardous Substances Data)
Toxicity
citrus red is a color used for coloring the skin of mature oranges. This compound has been described as being carcinogenic.
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1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Usage And Synthesis

Uses

To color orange skins.

Preparation

2,5-Dimethoxyaniline diazotization, and Naphthalen-2-ol coupling.

Definition

ChEBI: Citrus Red No.2 is a member of azobenzenes.

General Description

Orange to yellow solid or dark red powder.

Air & Water Reactions

Azo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.

Reactivity Profile

1-[(2,5-dimethoxyphenyl)azo]-2-naphthol is an azo compound. Toxic gases are formed by mixing compounds containing azo groups with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Hazard

Possible carcinogen.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition it emits toxic fumes of NOx.

Fire Hazard

Flash point data for 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol are not available. 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol is probably combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx

Properties and Applications

orange to red. Melting point of 155 ~ 157 ℃. Slightly soluble in water, slightly soluble in ethanol and rape oil.

1-[(2,5-dimethoxyphenyl)azo]-2-naphtholSupplier

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