Basic information Safety Supplier Related

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Basic information Safety Supplier Related

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Basic information

Product Name:
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms:
  • (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol 95%
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-bi-2- naphthol, 98%e.e.
  • SF120021
  • [1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis[3,5-bis(trifluoromethyl)phenyl]-, (1R)-
CAS:
756491-54-0
MF:
C36H18F12O2
MW:
710.51
Product Categories:
  • BINOLs
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes
Mol File:
756491-54-0.mol
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties

Melting point:
216-220 °C
Boiling point:
574.7±50.0 °C(Predicted)
Density 
1.466±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
solid
pka
7.62±0.50(Predicted)
color 
White to yellow
optical activity
[α]22/D 45°, c = 1 in chloroform
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29081990
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Usage And Synthesis

Chemical Properties

Colorless solid

Uses

Precursor to a chiral Bronsted acid (680184) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Supplier

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