1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE Chemical Properties

Melting point:

>300

storage temp. 

Inert atmosphere,Room Temperature

form 

Powder

color 

White

InChI

InChI=1S/C27H39N2.BF4/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2-1(3,4)5/h9-14,17-21H,15-16H2,1-8H3;/q+1;-1

InChIKey

KFZBJQUHHALFSR-UHFFFAOYSA-N

SMILES

C1(=C(C(C)C)C=CC=C1C(C)C)N1CC[N+](C2C(C(C)C)=CC=CC=2C(C)C)=C1.[B-](F)(F)(F)F

Safety Information

Hazard Codes 

C

Risk Statements 

20-34

Safety Statements 

26-36/37/39-45

RIDADR 

UN 1759 8/PG 2

WGK Germany 

3

TSCA 

No

HS Code 

29332990

1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE Usage And Synthesis

Reaction

In-situ deprotonation leads to metal carbene species which acts as a catalyst in a variety of C-C and C-N bond forming reactions.

1. Ligand used in the nickel or palladium-catalyzed coupling of aryl chlorides and amines.
2. Ligand used for the palladium-catalyzed arylation of esters and amides.
3. Ligand used for the palladium-catalyzed intermolecular amination of Csp3–H Bonds.
4. Ligand used for the nickel-catalyzed hydrogenation of olefins. 

1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE(282109-83-5)Related Product Information

• Sodium dodecyl sulfate
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• 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
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• Benzenamine, 2,6-diethyl-N-methylene-
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• 1,3-BIS(2,6-DI-I-PROPYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE