PHENYLMAGNESIUM CHLORIDE Chemical Properties

Melting point:

89-90℃

Boiling point:

230℃ (8 Torr)

Density 

0.98 g/mL at 20 °C

Flash point:

1 °F

storage temp. 

2-8°C

Water Solubility 

It reacts violently with water.

Sensitive 

Air & Moisture Sensitive

Merck 

14,7298

BRN 

3587900

InChIKey

GQONLASZRVFGHI-UHFFFAOYSA-M

CAS DataBase Reference

100-59-4(CAS DataBase Reference)

EPA Substance Registry System

Magnesium, chlorophenyl- (100-59-4)

Safety Information

Hazard Codes 

F,C

Risk Statements 

14-19-20/21/22-34-67-65-63-48/20-11-40-37

Safety Statements 

26-36/37/39-45-62-33-16

RIDADR 

UN 2924 3/PG 2

WGK Germany 

2

F 

10

TSCA 

Yes

HazardClass 

8

PackingGroup 

II

HS Code 

29319090

Hazardous Substances Data

100-59-4(Hazardous Substances Data)

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

PHENYLMAGNESIUM CHLORIDE Usage And Synthesis

Chemical Properties

yellowish-brown to dark brown solution

Uses

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl₃) in the rechargeable magnesium batteries.

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.

Definition

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.

General Description

This product has been enhanced for energy efficiency.

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