Acrolein dimethyl acetal Chemical Properties

Boiling point:

89-90 °C(lit.)

Density 

0.862 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.395(lit.)

Flash point:

27 °F

storage temp. 

2-8°C

form 

clear liquid

color 

Colorless to Almost colorless

BRN 

1700037

LogP

0.653 (est)

CAS DataBase Reference

6044-68-4(CAS DataBase Reference)

NIST Chemistry Reference

Acrolein,dimethyl acetal(6044-68-4)

Safety Information

Hazard Codes 

F

Risk Statements 

11

Safety Statements 

16-23-24/25-29-33

RIDADR 

UN 3384 6.1/PG 1

WGK Germany 

3

RTECS 

UC8500000

HazardClass 

3.1

PackingGroup 

II

HS Code 

2911000000

MSDS

• Language:English Provider:3,3-Dimethoxy-1-propene
• Language:English Provider:SigmaAldrich

Acrolein dimethyl acetal Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Acrolein dimethyl acetal was used in the facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction with octen-3-ol.

Purification Methods

Fractionally distil it (after adding 0.5g of hydroquinone) under reduced pressure through an all glass column (40cm x 2.5 cm) packed with glass helices and provided with a heated jacket and a total reflux variable take-off head. Stainless steel Lessing rings (1/8 x 1/8 in) or gauze have also been used as packing. It is a highly flammable and TOXIC liquid; keep away from the skin. [Hall & Stern J Chem Soc 2657 1955, Beilstein 1 IV 3437.]

Acrolein dimethyl acetal (6044-68-4)Related Product Information

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