Basic information Reactions Safety Supplier Related

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

Basic information Reactions Safety Supplier Related

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Basic information

Product Name:
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
Synonyms:
  • RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]
  • Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen]
  • Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
  • RuCl2[(S)-xylbinap][(S,S)-dpen]
  • -binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
  • DICHLORO{(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(
  • Dichloro[(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(S,S)-1,2-diphenylethylenediamine]ruthenium(II)
  • (S) -DM-BINAP RUCL2 (S.S)-DPEN
CAS:
220114-03-4
MF:
C66H64Cl2N2P2Ru
MW:
0
Product Categories:
  • Ru
Mol File:
220114-03-4.mol
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Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Chemical Properties

storage temp. 
2-8°C
form 
Powder
color 
yellow
Sensitive 
air sensitive
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Safety Information

WGK Germany 
3
HS Code 
2843.90.0000
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Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Usage And Synthesis

Reactions

  1. Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
  2. Asymmetic hydrogenation of imines.
  3. Catalysts for deracemization of benzylic alcohols. 

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)Supplier

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