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Orange IV

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Orange IV Basic information

Product Name:
Orange IV
Synonyms:
  • 4-[[4-(phenylamino)phenyl]azo]-benzenesulfonicacimonosodiumsalt
  • Benzenesulfonicacid,4-[[4-(phenylamino)phenyl]azo]-,monosodiumsalt
  • c.i.acidorange5,
  • c.i.acidorange5,monosodiumsalt
  • OrangeⅣ
  • sodium 4-[[4-(anilino)phenyl]azo]benzenesulphonate
  • TROPAEOLIN OO INDICATOR
  • OrangeIvC.I.13080
CAS:
554-73-4
MF:
C18H16N3NaO3S
MW:
377.39
EINECS:
209-071-4
Product Categories:
  • Indicator (pH)
  • pH Indicators
  • Analytical Chemistry
  • Azo
Mol File:
554-73-4.mol
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Orange IV Chemical Properties

Melting point:
>300°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Solubility Soluble in water, ethanol
Colour Index 
13080
form 
Powder
pka
2.0(at 25℃)
color 
S. No.: 179
PH Range
1.3(red)-3.2(yellow)
λmax
527nm, 443nm
Merck 
14,9776
Stability:
Stable. Incompatible with strong oxidizing agents.
Major Application
Sensors, lithographic plates, optical recording media, photoreceptor, inks, indication system for product exceeding threshold temperature, lubricants, textiles, food storage, determination of amiodarone, astemizole, bromhexine, clomipramine, deutiforin, domperidone, fluoroquinolone, roxithromycin, terfenadine, thiabendazole, antihistamines
CAS DataBase Reference
554-73-4(CAS DataBase Reference)
EPA Substance Registry System
Benzenesulfonic acid, 4-[[4-(phenylamino)phenyl]azo]-, monosodium salt (554-73-4)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-41-37/38-22
Safety Statements 
36/37-26-36/37/39-36-24/25
HazardClass 
IRRITANT
HS Code 
29270000

MSDS

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Orange IV Usage And Synthesis

Chemical Properties

yellow-brown or orange powder

Uses

As indicator. pH: red 1.4 to yellow 2.6.

Preparation

ommonly known as acidic orange IV. 4-Aminobenzenesulfonic acid diazo, with Diphenylamine coupling.

Properties and Applications

yellow orange. Soluble in water and ethanol for orange, slightly soluble in ethyl ether, insoluble in benzene. The strong sulfuric acid is purple, dilute appears after the purple precipitation. In water solution to join hydrochloric acid appear purple precipitation; With sodium hydroxide appear yellow precipitation. Used for wool, silk, cotton, vinegar fiber etc fiber dyeing. Can also be used to indicator, paper, soap kind, straw and leather color. Good levelness, discharge sex medium, dyeing encounter copper, iron ion color shade darker.

Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 3 1-2 2 1-2 1-2

Purification Methods

Recrystallise it twice from water [Kolthoff & Gus J Am Chem Soc 60 2516 1938]. [Beilstein 16 II 171.]

Orange IVSupplier

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